| 218600-12-5

• CAS: 218600-12-5
• 化学式: C₂₁H₄₂O₃P₆W
• 分子量: 712.255
• InChiKey: JTTGFEVHVJQUKD-HFIZVTBBSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  yellow phosphorus 、 W(CO)3(P(isopropyl)3)2 以 甲苯 为溶剂， 以58%的产率得到
  参考文献：
  名称：

  Complexes with a Monohapto Bound Phosphorus Tetrahedron and Phosphaalkyne¹

  摘要：

  The reaction. of white phosphorus with the coordinatively unsaturated [M(CO)(3)(PR3)(2)] complexes (M = Mo, W; R = Cy, Pr-i) yields the compounds [M(CO)(3)(PR3)(2)(eta(1)-P-4)] in, which the P-4-tetrahedron is end-on bonded to the metal. In. the same manner reacts Ar'C=P (Ar' = C6H2Bu3t-2,4,6) with this complex to give [W(CO)(3)(PCy3)(2)(eta(1)-P=CAr')]. The X-ray structures of the products are discussed, and for the P-4-unit in [W(CO)(3)(PCy3)(2)(eta(1)-P-4)] the librational analysis was performed to correct their translational and rotational motions.

  DOI：

  10.1021/om9806794