Neodymium--nickel (1/5) | 12423-51-7

• 分子结构分类: 无机化合物 - 均相金属化合物 - 金属间镧系化合物
• 英文名称: Neodymium--nickel (1/5)
• 英文别名: neodymium;nickel
• CAS: 12423-51-7
• 化学式: NdNi₅
• 分子量: 437.69
• InChiKey: SCISMUOCCPYZJE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.01
• 重原子数：
  6
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  Neodymium--nickel (1/5) 、 以 neat (no solvent) 为溶剂， 生成
  参考文献：
  名称：

  Synthesis and structure determination of a new series of hydrogen storage alloys; RMg2Ni9 (R=La, Ce, Pr, Nd, Sm and Gd) built from MgNi2 Laves-type layers alternating with AB5 layers

  摘要：

  A number of new ternary magnesium based alloys, RMg2Ni9 (where R=La, Ce, Pr, Nd, Sm and Gd), have been synthesized by reacting a mixture of MgNi2 with RNi5 intermetallic compounds or by direct combination of the elements in the atomic ratio R:Mg:Ni=1:2:9. The crystal structure, determined by Guinier-Hagg X-ray powder diffraction, is related to the hexagonal PuNi3 type. All interatomic distances are close to the corresponding ones in (C-15) MgCu2, (C-14) MgZn2, (C-36) MgNi2, RNi3 and RNi5 of metallic-type bonding. (C) 1997 Elsevier Science S.A.

  DOI：

  10.1016/s0925-8388(96)03132-5
• 作为产物：
  描述：

  氟化钕 、 Neodymium--nickel (1/2) 在 LiF 、 CaF₂ 作用下， 以 melt 为溶剂， 生成 Neodymium--nickel (1/5)
  参考文献：
  名称：

  Nd-Ni合金在熔融LiF-CaF2-NdF3中的电化学形成

  摘要：

  The electrochemical formation of Nd-Ni alloys was investigated in a molten LiF-CaF2-NdF3 (0.30 mol %) system at 1123 K. Cyclic voltammetry and open-circuit potentiometry indicated the formation of several phases of Nd-Ni alloys. Potentiostatic electrolysis was conducted to prepare an alloy sample using a Ni plate electrode at 0.15 V vs. Li+/Li for 75 min. Cross-sectional scanning electron microscopy revealed that the entire Ni plate was transformed into Nd-Ni alloy. X-ray diffraction analysis confirmed that the alloy consisted predominantly of the NdNi2 phase with NdNi3 as the minor phase. When the electrolytic potential was changed to 0.35 V and 0.60 V after electrolysis at 0.15 V for 75 min, the resultant phases were NdNi3 and NdNi5, respectively. The formation potential for each Nd-Ni alloy phase was determined from the experimental results. (C) 2011 The Electrochemical Society. [DOI: 10.1149/2.072112jes] All rights reserved.

  DOI：

  10.1149/2.072112jes

文献信息

• Cocktail effect on RT5-type (R = rare earth, T = 3d transition metal) high entropy intermetallic compounds
  作者：Linhan Yin、Yongquan Guo、Xinpeng Guo

  DOI：10.1016/j.jmmm.2022.169883

  日期：2022.12

  intermetallic compounds due to their single-phase characteristics and high configuration entropy. The magnetic cocktail effect is observed in magnetic measurements. These intermetallic compounds show low-temperature magnetic transition and field-induced ferromagnetic characteristics. The cocktail effect is suggested to be modulated by the spins with random directions at rare earth and transition metal sublattices

  正常成分为（Sm1/2Ce1/2）（Co1/3Cu1/3Ni1/3）5、（Sm1/2Pr1/2）（Co1/3Cu1/3Ni1/3）5、（Sm1/2Nd1/2）（Co1/3Cu1/3Ni1/3）5、（Sm1/3Ce1/3Pr1/3）（Co1/3Cu1/3Ni1/3）5和（Sm1/3Ce1/3Nd1/3）（Co1/3Cu1/3 Ni1/3）5的合金是通过混合RCo5、RNi5设计的。 和 RCu5 用于研究它们的鸡尾酒效果。这些设计的合金是通过真空电弧熔炼技术制备的。它们的单相特性通过具有能量色散光谱的 X 射线衍射和扫描电子显微镜进行了实验证实，也被报道的高熵合金单相形成规则理论证实了：原子半径差在 6% 以内，非正混合焓，高构型熵在 1.50R 以上。由于其单相特性和高构型熵，所设计的合金被认为是高熵金属间化合物。在磁性测量中观察到磁性混合物效应。这些金属间化合物表现出低温磁转变和场感应铁
• Electrode characteristics of nanocrystalline AB5 compounds prepared by mechanical alloying
  作者：Z. Chen、Z. Chen、Y. Su、M. Lü、D. Zhou、P. Huang

  DOI：10.1016/s0025-5408(98)00134-2

  日期：1998.10

  Nanocrystalline LaNi(5) and LaNi(4.5)Si(0.5) synthesized by mechanical alloying were used as negative materials for Ni-MH batteries. It was found that the electrodes prepared with the nanocrystalline powders had similar discharge capacities, better activation behaviors, and longer cycle lifetimes, compared with the negative electrode prepared with polycrystalline coarse-grained LaNi(5) alloy. The properties of the electrodes prepared with these nanocrystalline materials were attributed to the structural characteristics of the compounds caused by mechanical alloying. (C) 1998 Elsevier Science Ltd.
• Catalytic and sorptional properties of LnNi5 intermetallic compounds
  作者：I. R. Konenko、N. M. Parfenova、E. I. Klabunovskii、E. M. Savitskii、V. P. Mordovin、T. P. Makarochkina

  DOI：10.1007/bf00955277

  日期：1981.5
• Magnetocaloric effect in the<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mrow><mml:mi>R</mml:mi><mml:msub><mml:mi mathvariant="normal">Ni</mml:mi><mml:mn>5</mml:mn></mml:msub></mml:mrow></mml:math>(<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mrow><mml:mi>R</mml:mi><mml:mo>=</mml:mo><mml:mi mathvariant="normal">Pr</mml:mi></mml:mrow></mml:math>, Nd, Gd, Tb, Dy, Ho, Er) series
  作者：P. J. von Ranke、M. A. Mota、D. F. Grangeia、A. Magnus G. Carvalho、F. C. G. Gandra、A. A. Coelho、A. Caldas、N. A. de Oliveira、S. Gama

  DOI：10.1103/physrevb.70.134428

  日期：——

  In this paper, the magnetocaloric effect in the hexagonal intermetallic compounds belonging to the RNi5 series was calculated using a Hamiltonian including the crystalline electrical field, exchange interaction, and the Zeeman effect. Experimental work was performed and the two thermodynamics quantities, namely, isothermal entropy change and adiabatic temperature change were obtained for polycrystalline samples, using heat capacity measurements, and compared to the theoretical predictions.
• ——
  作者：A. G. Burlakova、L. S. Volkov、S. P. Shilkin

  DOI：10.1023/a:1026365118722

  日期：——

  The possibility of obtaining powdered LaNi5 and NdNi5 intermetallic compounds by reaction of mixed basic carbonates La2Ni10(CO3)(8)(OH)(10) . 54H(2)O and Nd2Ni10(CO3)8(OH)(10) . 14H(2)O with calcium hydride in a hydrogen flow at 1073 K and 10(5) Pa was studied.