Cerium;copper | 12157-55-0

• 分子结构分类: 无机化合物 - 均相金属化合物 - 金属间镧系化合物
• 英文名称: Cerium;copper
• 英文别名: cerium;copper
• CAS: 12157-55-0
• 化学式: CeCu₄
• 分子量: 394.304
• InChiKey: BIKSNLJGOXNHMI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.01
• 重原子数：
  5
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  铜 、 氢化铈 (CeH3) 以 melt 为溶剂， 生成 Cerium;copper
  参考文献：
  名称：

  Experimental investigation of the Ce–Cu phase diagram

  摘要：

  The binary Ce-Cu system has been re-investigated via the selected eighteen key alloys by means of the differential scanning calorimetry (DSC), X-ray diffraction (XRD), and scanning electron microscopy (SEM) with energy dispersive X-ray analysis techniques. Five intermetallic compounds, Cu6Ce, Cu5Ce, Cu4Ce, Cu2Ce, and CuCe, have been confirmed. Cu6Ce and Cu2Ce melt congruently at 947 degrees C and 810 degrees C, respectively. Cu5Ce, Cu4Ce, and CuCe are formed through peritectic reactions, L + Cu6Ce <-> Cu5Ce at 799 degrees C, L + Cu5Ce <-> Cu4Ce at 792 degrees C, and L + Cu2Ce <-> CuCe at 492 degrees C, respectively. Three eutectic reactions, L <-> (Cu) + Cu6Ce at 879 degrees C, L <-> Cu4Ce + Cu2Ce at 753 degrees C, and L <-> CuCe + (gamma Ce) at 407 degrees C, have been observed. One catatectic reaction, (delta Ce) <-> L + (gamma Ce) at 702 degrees C, was determined. According to the present experimental results, the Ce-Cu phase diagram is revised. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jallcom.2011.09.054

文献信息

• Experimental investigation of the Ce–Cu phase diagram
  作者：Huaiying Zhou、Chengying Tang、Minmin Tong、Zhengfei Gu、Qingrong Yao、Guangfei Rao

  DOI：10.1016/j.jallcom.2011.09.054

  日期：2012.1

  The binary Ce-Cu system has been re-investigated via the selected eighteen key alloys by means of the differential scanning calorimetry (DSC), X-ray diffraction (XRD), and scanning electron microscopy (SEM) with energy dispersive X-ray analysis techniques. Five intermetallic compounds, Cu6Ce, Cu5Ce, Cu4Ce, Cu2Ce, and CuCe, have been confirmed. Cu6Ce and Cu2Ce melt congruently at 947 degrees C and 810 degrees C, respectively. Cu5Ce, Cu4Ce, and CuCe are formed through peritectic reactions, L + Cu6Ce <-> Cu5Ce at 799 degrees C, L + Cu5Ce <-> Cu4Ce at 792 degrees C, and L + Cu2Ce <-> CuCe at 492 degrees C, respectively. Three eutectic reactions, L <-> (Cu) + Cu6Ce at 879 degrees C, L <-> Cu4Ce + Cu2Ce at 753 degrees C, and L <-> CuCe + (gamma Ce) at 407 degrees C, have been observed. One catatectic reaction, (delta Ce) <-> L + (gamma Ce) at 702 degrees C, was determined. According to the present experimental results, the Ce-Cu phase diagram is revised. (C) 2011 Elsevier B.V. All rights reserved.