(η5-1,1-bis(p-anisyl)-2-cyclopentadienyl-butene)tricarbonylrhenium | 259533-89-6

• 英文名称: (η5-1,1-bis(p-anisyl)-2-cyclopentadienyl-butene)tricarbonylrhenium
• CAS: 259533-89-6
• 化学式: C₂₆H₂₃O₅Re
• 分子量: 601.673
• InChiKey: SOWMWNOQLHZZLA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  五羰基溴铼(I) 、 以45%的产率得到(η5-1,1-bis(p-anisyl)-2-cyclopentadienyl-butene)tricarbonylrhenium
  参考文献：
  名称：

  有机金属环戊二烯基系列中的新型温和金属交换反应：以 1,1'-二芳基 2-Cymantrenyl 1-Butene 为例

  摘要：

  DOI：

  10.1021/ja991915k

文献信息

• Decomplexation of Cyclopentadienylmanganese Tricarbonyls under Very Mild Conditions:  A Novel Route to Substituted Cyclopentadienes and Their Application in Organometallic Synthesis
  作者：Siden Top、El Bachir Kaloun、Stéphanie Toppi、Audrey Herrbach、Michael J. McGlinchey、Gérard Jaouen

  DOI：10.1021/om010274a

  日期：2001.10.1

  attempted decomplexation using Ce(IV) or Fe(III) leads merely to decomposition products. It is proposed that, upon photolytic loss of a CO ligand, coordination of methanol or water facilitates an intramolecular proton transfer to the cyclopentadienyl ring. This method is applicable to polyfunctional molecules such as ethynylestradiol. In this new synthetic approach, these cymantrenes have also been

  在质子源的存在下，环戊二烯基锰三羰基锰衍生物的光解导致络合和游离环戊二烯的形成，产率很高。相反，尝试使用Ce（IV）或Fe（III）进行的络合仅导致分解产物。提出在CO配体的光解损失后，甲醇或水的配位促进分子内质子转移至环戊二烯基环。该方法适用于诸如乙炔雌二醇等多官能分子。在这种新的合成方法中，这些半胱氨酸还通过生成中间环戊二烯而用作相应的铁，钨，钛和rh配合物的前体。
• Reaction of [Re(CO)6]+ cation with cyclopentadienylthallium derivatives. Formation of cyclopentadienylrheniumtricarbonyl derivatives via [Re(CO)3L3]+ (L=solvent)
  作者：Stéphane Masi、Siden Top、Gérard Jaouen

  DOI：10.1016/s0020-1693(03)00110-5

  日期：2003.7

  The reaction of [Re(CO)(6)](+) with cyclopentadienylthallium derivatives in DMSO or in DMF affords the corresponding cyclopentadienyltricarbonylrhenium derivatives with high yields. The cyclopentadienyl transfer from CpTl to [Re(CO)(6)][BF4] was also carried out in acetonitrile. However, in this case it is necessary to work in a sealed tube heated at 160 degreesC. Two compounds are obtained: the expected CpRe(CO)(3) and a rhenium salt which was identified as [Re(CO)(3)(CH3CN)(3)][BF4]. The triacetonitrile tricarbonyl cation fac-[Re(CO)(3)(CH3CN)(3)](+) is also formed upon dissolution of [Re(CO)(6)][BF4] in acetonitrile and heating at 160 degreesC under pressure. It reacts afterwards with CpTl in acetonitrile to yield CpRe(CO)(3) (32%). Thus, [Re(CO)(3)(CH3CN)(3)][BF4] can be considered as an intermediate for this ligand-transfer reaction. (C) 2003 Elsevier Science B.V. All rights reserved.