[(η6-C5Me4CH2)RuCl2(CH3CN)] | 1020225-32-4

• 英文名称: [(η6-C5Me4CH2)RuCl2(CH3CN)]
• CAS: 1020225-32-4
• 化学式: C₁₂H₁₇Cl₂NRu
• 分子量: 347.25
• InChiKey: BLWHXCXQJCGBPT-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  [(η6-C5Me4CH2)RuCl2(CH3CN)] 、 苯甲酸 以 乙腈 为溶剂， 以92%的产率得到[(η6-benzoic acid)Ru(η5-C5Me4CH2OH)]Cl
  参考文献：
  名称：

  [(η⁵-C₅Me₄CH₂R)Ru(η⁶-arene)]⁺ and [(η⁵-C₅Me₄CH₂R)Ru(CH₃CN)₃]⁺ Compounds Possessing Pendant Arms

  摘要：

  [(eta(5)-C5Me4CH2)Ru(eta(6)-arene)](+) , [eta(5)-C5Me4CH2R)Ru(CH3CN)(3)](+) (R = OH, OR, and NR1R2), and related compounds possessing pendant arms are synthesized by the attack of water, alcohol, alkoxide, or amine nucleophiles on the methylenic carbon atoms of the readily available tetramethylfulvene complex [(eta(6)-C5Me4CH2)(RuCl)-Cl-11(mu-Cl)](2) (1) or its simple acetonitrile derivative, [(eta(6)-C5Me4CH2)Ru-11(CH3CN)Cl-2] (1a). The [(eta(5)-C5Me4CH2R)Ru (eta(6)-arene)](+) compounds can generally be quantitatively converted back into [(eta(5)-C5Me4CH2R)Ru(CH3CN)(3)](+) species by UV photolysis in CH3CN.

  DOI：

  10.1021/om701084m
• 作为产物：
  描述：

  [((η(6)-C5Me4CH2)RuCl2)2] 、 乙腈 以 not given 为溶剂， 以95%的产率得到[(η6-C5Me4CH2)RuCl2(CH3CN)]
  参考文献：
  名称：

  [(η⁵-C₅Me₄CH₂R)Ru(η⁶-arene)]⁺ and [(η⁵-C₅Me₄CH₂R)Ru(CH₃CN)₃]⁺ Compounds Possessing Pendant Arms

  摘要：

  [(eta(5)-C5Me4CH2)Ru(eta(6)-arene)](+) , [eta(5)-C5Me4CH2R)Ru(CH3CN)(3)](+) (R = OH, OR, and NR1R2), and related compounds possessing pendant arms are synthesized by the attack of water, alcohol, alkoxide, or amine nucleophiles on the methylenic carbon atoms of the readily available tetramethylfulvene complex [(eta(6)-C5Me4CH2)(RuCl)-Cl-11(mu-Cl)](2) (1) or its simple acetonitrile derivative, [(eta(6)-C5Me4CH2)Ru-11(CH3CN)Cl-2] (1a). The [(eta(5)-C5Me4CH2R)Ru (eta(6)-arene)](+) compounds can generally be quantitatively converted back into [(eta(5)-C5Me4CH2R)Ru(CH3CN)(3)](+) species by UV photolysis in CH3CN.

  DOI：

  10.1021/om701084m