[(Re(CO)3Br)2(μ-N,N'-bis(2,2'-bipyridin-5'-ylcarbonyl)-2-[2-(2-aminoethoxy)ethoxy]ethylamine)] | 942922-72-7

• 英文名称: [(Re(CO)3Br)2(μ-N,N'-bis(2,2'-bipyridin-5'-ylcarbonyl)-2-[2-(2-aminoethoxy)ethoxy]ethylamine)]
• CAS: 942922-72-7
• 化学式: C₃₄H₂₈Br₂N₆O₁₀Re₂
• 分子量: 1212.85
• InChiKey: WBWKKMWWLIPRFX-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  五羰基溴铼(I) 、 N,N'-bis(2,2'-bipyridin-5-ylcarbonyl)-2-[2-(2-aminoethoxy)ethoxy]ethylamine 以 甲苯 为溶剂， 以80%的产率得到[(Re(CO)3Br)2(μ-N,N'-bis(2,2'-bipyridin-5'-ylcarbonyl)-2-[2-(2-aminoethoxy)ethoxy]ethylamine)]
  参考文献：
  名称：

  Anion Detection Driven by a Surprising Internal Hydrogen-Bonding Association in a Dinuclear Rhenium(I) Complex

  摘要：

  A neutral dinuclear rhenium(I) bipyridinetricarbonyl bromide complex has been investigated with a range of anions, giving a remarkable binding affinity for dihydrogenphosphate. These studies highlight that anion sensing can be achieved with structurally simple species provided that the compound adopts an unconventional conformation, through, for example, intramolecular hydrogen bonding in solution.

  DOI：

  10.1021/ic700452k