| 155941-81-4

• CAS: 155941-81-4
• 化学式: C₂₃H₂₈NO₄Re
• 分子量: 568.687
• InChiKey: WWDBNUJLQBNPMF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  在 吡啶 作用下， 以 乙醚 为溶剂， 以95%的产率得到
  参考文献：
  名称：

  用三氟甲基磺酸从酰基中提取“ O2-”来合成2，（V）2,4,6-三甲基苄二炔配合物

  摘要：

  Re[C(O)Ar'](CO)5 (Ar' = 2,4,6-C6H2Me3; 1) can be prepared in 55% yield by adding ArC(O)Cl to [Re(CO)5]-. Addition of trifluoromethanesulfonic anhydride to 1 in dichloromethane yields off-white [Re(CAr')(CO)4(OTf)](OTf) (2) quantitatively. Three equivalents of tetraethylammonium chloride reacts with 2 in dichloromethane to give [Et4N[Re(CAr)(CO)2Cl3] (3), which when treated with TlBF4 in the presence of pyridine affords lemon yellow Re(CAr')(CO)2Cl2(py)(4). A slurry of 2 in dichloromethane also reacts cleanly with a THF solution of LiO-2,6-C6H3-i-Pr2 (LiOAr) to yield blood red Re(CAr')(CO)2(OAr)2(THF) (5a) in 80% isolated yield. Addition of pyridine to 5a yields an analogous six-coordinate pyridine adduct (5b). Addition of pinacol to 2 followed by triethylamine yields yellow, pentane-soluble Re(CAr')(CO)2(O2C2Me4) (6a). Although 6a shows no tendency to bind THF, it reacts with pyridine to yield Re(CAr')(CO)2(O2C2Me4)(py) (6b) quantitatively. Addition of triphenylphosphine to 6a produces dark red Re(CAr')(CO)(O2C2Me4)(PPh3) (6c).

  DOI：

  10.1021/om00017a080