dichloropentaphenoxy(2-pyridylethylamino)cyclotriphosphazeneplatinum(II) | 924278-10-4

• 英文名称: dichloropentaphenoxy(2-pyridylethylamino)cyclotriphosphazeneplatinum(II)
• 英文别名: dichloro[pentaphenoxy(2-(2-pyridyl)ethylamino)cyclotriphosphazene]platinum(II)
• CAS: 924278-10-4
• 化学式: C₃₇H₃₄Cl₂N₅O₅P₃Pt
• 分子量: 987.615
• InChiKey: OABJDTGYKKDLAH-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  bis(acetonitrile)dichloroplatinum(II) 、 pentaphenoxy(2-pyridylethylamino)cyclotriphosphazene 以 乙腈 为溶剂， 以22.8%的产率得到dichloropentaphenoxy(2-pyridylethylamino)cyclotriphosphazeneplatinum(II)
  参考文献：
  名称：

  Reactions of platinum nitrile complexes with cyclotriphosphazenes containing pyridylalkylamino groups

  摘要：

  Reactions of platinum(II) and platinum(IV) nitrile complexes with polydentate ligands, such as pentaphenoxy(2-pyridylmethylamino)cyclotriphosphazene, pentaphenoxy(3-pyridylmethylamino)cyclotriphosphazene, and pentaphenoxy(2-pyridylethylamino)cyclotriphosphazene, were studied. Platinum(IV) is reduced to platinum(II) upon complex formation; the pyridine and alkylamine nitrogen atoms coordinate to platinum(II) to form chelate rings. The compounds obtained were characterized by H-1 and P-31 NMR and IR spectroscopy, FAB mass spectrometry, and other methods.

  DOI：

  10.1134/s1070363206040074

文献信息

• Synthesis and molecular structure of platinum(II) complexes with cyclotriphosphazenes containing pyridylalkylamino and pyridylmethoxy groups
  作者：S. A. Simanova、T. V. Kuznetsova、V. N. Demidov、E. A. Aleksandrova、U. Diefenbach

  DOI：10.1134/s1070363207110059

  日期：2007.11

  The interaction of platinum(II) nitrile complexes with polydentate ligands, pentaphenoxy(2-pyridylmethylamino) cyclotriphosphazene (L-1), pentaphenoxy( 3-pyridylmethylamino) cyclotriphosphazene (L-2), pentaphenoxy[2-(2- pyridyl) ethylamino] cyclotriphosphazene (L-3), and pentaphenoxy(2-pyridylmethoxy)cyclotriphosphazene (L-4), was studied. The synthesized complexes were characterized by single-crystal X-ray diffraction, H-1 and P-31 NMR spectroscopy, IR spectroscopy, FAB mass spectrometry, and other methods. In complexation of phosphazenes L-1 L-3 with Pt(II) ions, nitrogen atoms of the pyridine ring and alkylamine fragment participate in the coordination to form chelate rings. In the complex with L-4, the substituted phosphazene is coordinated via nitrogen atoms of the pyridyl group and cyclotriphosphazene ring to form a seven-membered ring.