trans-[Cd(acetone 4-phenylsemicarbazone)2(chloride)2] | 1238844-89-7

• 英文名称: trans-[Cd(acetone 4-phenylsemicarbazone)2(chloride)2]
• CAS: 1238844-89-7
• 化学式: C₂₀H₂₆CdCl₂N₆O₂
• 分子量: 565.781
• InChiKey: HQFWZXQKTSGCQR-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  acetone 4-phenylsemicarbazone 、 cadmium(II) chloride 以 甲醇 为溶剂， 生成 trans-[Cd(acetone 4-phenylsemicarbazone)2(chloride)2]
  参考文献：
  名称：

  Synthesis and spectral characterization of zinc(II) and cadmium(II) complexes of acetone-N(4)-phenylsemicarbazone: Crystal structures of acetone-N(4)-phenylsemicarbazone and a cadmium(II) complex

  摘要：

  Seven Zn(II) and Cd(II) complexes of ON donor acetone-N(4)-phenylsemicarbazone (HL) have been synthesized and physico-chemically characterized by partial elemental analyses, molar conductance measurements, infrared, electronic and H-1 NMR spectral studies. The semicarbazone binds the metal as a neutral bidentate ligand in all the complexes. The crystal structures of acetone-N(4)-phenylsemicarbazone and [Cd(HL)(2)Cl-2] have been determined by X-ray diffraction studies. The coordination geometry around cadmium(II) in the complex [Cd(HL)(2)Cl-2] is distorted octahedral. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2010.03.011