[2,2-(PPh3)2-2-H-closo-2,1-RhSB10H10] | 61796-42-7

• 英文名称: [2,2-(PPh3)2-2-H-closo-2,1-RhSB10H10]
• CAS: 61796-42-7
• 化学式: C₃₆H₄₁B₁₀P₂RhS
• 分子量: 778.751
• InChiKey: QIRPEXWGYSXBKG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  [2,2-(PPh3)2-2-H-closo-2,1-RhSB10H10] 、 二氯甲烷 、 二甲基苯基磷 以 二氯甲烷 为溶剂， 以20%的产率得到[2,2-(PMe2Ph)2-2-Cl-closo-2,1-RhSB10H10]
  参考文献：
  名称：

  Polyhedral metallathiaborane chemistry: Synthesis and characterisation of metallathiaboranes based on the twelve-vertex icosahedral closo-{MSB10H10} unit, where M is Rh or Ir

  摘要：

  The reaction of [nido-7-SB10H12] With [RhCl(PPh3)(3)] ill the presence of N,N,N'N'-tetramethylnaphthalene-1,8-diamine (tmnd) in CH2Cl2 gives twelve-vertex [2,2-(PPh3)(2)-2-H-closo-2,1-RhSB10H10] (1) and eleven-vertex [8,8-(PPh3)(2)-nido-8,7-RhSB9H10] (2), as major products, plus the dimeric species [{(PPh3)-closo-RhSB10H10)(2)] (3) as a minor product. Reaction of 1 with PMe2Ph in CH2Cl2 results in phosphine exchange and hydride substitution, affording the chloro analogue of 1, [2,2-(PMe2Ph)(2)-2-Cl-closo-2,1-RhSB10H10] (4). By contrast, reaction between [IrCI(PPh3)(3)] and [nido-7-SB10H12] in CH2C12 With timid affords only one product, twelve-vertex (2,2(PPh3)(2)-2-H-(closo-2,1-IrSB10H10] (5). [RuCl2(eta(5)-C5Me5)](2) with [nido-7-SB10H12] under the same conditions gives twelve-vertex [2-(eta(5)- C5Me5)-closo-2,1-RhSB10H10] (6). All the compounds are characterised by NMR spectroscopy, and by mass spectrometry, and the molecular structure of [2,2-(PMe2Ph)(2)-2-Cl-closo-2,1-RhSB10H10] (4) was established by single-crystal X-ray diffraction analysis. This last rhodathiaborane 4 is fluxional in solution through a process that involves a reversible partial rotation of the {RhCl(PMe2Ph)(2)} unit above the {SB4} pentagonal face of the {SB10H10} fragment. (C) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2007.11.014
• 作为产物：
  描述：

  Wilkinson's catalyst 、 以 乙醇 为溶剂， 生成 [2,2-(PPh3)2-2-H-closo-2,1-RhSB10H10]
  参考文献：
  名称：

  Synthesis of (PPh₃)₂RhH(SB₁₀H₁₀) and 2-(L₂IrHCl)-SB_nH_n–1(L = PPh₃or AsPh₃) by oxidative addition of 7-SB₁₀H₁₁^–and closo-SB_nH_n(n= 9 or 11) to rhodium and iridium phosphines

  摘要：

  DOI：

  10.1039/c39760000770

文献信息

• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Rh: SVol.B3, 4.24.13.5, page 155 - 156
  作者：

  DOI：——

  日期：——