9-dimethylaminomethyl-o-carborane | 180462-31-1

• 英文名称: 9-dimethylaminomethyl-o-carborane
• CAS: 180462-31-1
• 化学式: C₅H₁₉B₁₀N
• 分子量: 201.323
• InChiKey: OCBNOAGYFZPKDJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  9-(N,N-dimethylcarbamyl)-o-carborane 在 lithium aluminium tetrahydride 、 三氯化铝 作用下， 以 乙醚 为溶剂， 以93%的产率得到9-dimethylaminomethyl-o-carborane
  参考文献：
  名称：

  Synthesis of some functional derivatives ofo- andm-carboranes

  摘要：

  Amides, amines, and alcohols were synthesized from 9-o- and 9-m-carboranecarboxylic chlorides. It follows from comparison of the H-1 NMR spectra of N,N-dimethyl-1-o- and -1-m-carboranecarboxamides and N,N-dimethyl-9-o- and -9-m-carboranecarboxamides that pi-bonding of the carborane polyhedron with the carbonyl group in 1-carboranyl dimethylamides is stronger than that in 9-carboranyl diethylamides. Oxidation of 9-hydroxymethyl-m-carborane with pyridinium chlorochromate gives 9-m-carboranylmethyl 9-m-carboranecarboxylate.

  DOI：

  10.1007/bf01435805