Mo(CO)4(1,2,4-tris(diphenylphosphino)benzene)Mo(CO)5 | 245337-61-5

• 英文名称: Mo(CO)4(1,2,4-tris(diphenylphosphino)benzene)Mo(CO)5
• CAS: 245337-61-5
• 化学式: C₅₁H₃₃Mo₂O₉P₃
• 分子量: 1074.62
• InChiKey: INEVVPGDBDBCNX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  1,2,4-tris(diphenylphosphino)benzene 、 molybdenum hexacarbonyl 以 二乙二醇二甲醚 为溶剂， 生成 Mo(CO)4(1,2,4-tris(diphenylphosphino)benzene) 、 Mo(CO)4(1,2,4-tris(diphenylphosphino)benzene)Mo(CO)5
  参考文献：
  名称：

  Synthesis and NMR spectra of derivatives of the polykis(diphenylphosphino)benzenes, (Ph2P)nC6H6−n [n=2 to 4]

  摘要：

  111 derivatives of the polykis(diphenylphosphino)benzenes, (Ph2P)(n)C6H6-n [n=2 to 4] obtained by oxidation or reaction with sulfur, selenium, iodomethane, M(CO)(6) [M=Cr, Mo, W], [codRh-mu-Cl](2), or (PhCN)(2)MCl2 [M=Pd, Pt], are reported together with their P-31 and selected other NMR parameters. The reactions generally follow predictable courses, although stereochemical factors affect the range of products obtained and can lead to significant structural distortion in extreme cases. The P-31 chemical shifts and more particularly vicinal coupling constants are also markedly influenced by such factors, to the extent that in species with three or more adjacent Ph2P moieties they may be of limited diagnostic value. (C) 1999 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(99)00101-1