ferrocenylC(CH3)2ferrocenyl-C.tplbond.CH | 936212-23-6

• 英文名称: ferrocenylC(CH3)2ferrocenyl-C.tplbond.CH
• CAS: 936212-23-6
• 化学式: C₂₅H₂₄Fe₂
• 分子量: 436.16
• InChiKey: VPUZRRQDTFTJDE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  ferrocenylC(CH3)2ferrocenyl-C.tplbond.CH 、 苯乙炔 在 copper(l) chloride 作用下， 以 吡啶 为溶剂， 以61%的产率得到ferrocenylC(CH₃)2ferrocenyl-C_.tplbond.C-C_.tplbond.C-phenyl
  参考文献：
  名称：

  Synthesis, molecular structure and reactivity of new π-conjugated diyne with ferrocenyl and phenyl units

  摘要：

  New pi-conjugated butadiynyl ligand FcC(CH3)(2)Fc'-C=C-C=C-Ph (L-1) has been synthesized and its reaction with Co-2(CO)(8) has been studied. New clusters [FcC(CH3)(2)Fc'-C=C-C=C-Ph][(Co-2(CO)(6)](n) [(1): n = 1; (2): n = 2] and [Fc-C=C-C=C-Ph][Co-2(CO)(6)](n) [(3): n = 1; (4): n = 2] were obtained by the reaction of ligands FcC(CH3)(2)Fc'-C=C-C=C-Ph (L-1) and Fc-C=C-C=C-Ph (L-2) with Co-2(CO)(8) respectively and the composition and structure of the clusters and ligands have been characterized by elemental analysis, FTIR, H-1 and C-13 NMR and MS. The crystal structures of compounds L-1, L-2, 2 and 4 have been determined by X-ray single crystal analysis. (c) 2006 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2006.09.044