| 210221-24-2

• CAS: 210221-24-2
• 化学式: C₃₇H₃₁N₃O₂PRuS*F₆P
• 分子量: 858.746
• InChiKey: NXNNPFHTORSLED-KINXHMOCSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2-吡啶甲酸 、 dichlororuthenium;N-(2-methylsulfanylphenyl)-1-pyridin-2-ylmethanimine;triphenylphosphane 、 lithium perchlorate 以 甲醇 、 水 为溶剂， 以70%的产率得到
  参考文献：
  名称：

  Synthesis, characterization and reactivity of cis-Ru (L)(PPh3) Cl2; L = 2-pyridyl-N-(2′-methylthiophenylmethyleneimine) crystal structure of cis-Ru(L)(PPh3)Cl2 and [Ru(L)(PPh3)(bpy)](ClO4)2

  摘要：

  A number of ruthenium(II) complexes containing an NNS chelating thioether ligand (L) have been synthesized and characterized by elemental analysis, UV-visible, IR and H-1 NMR spectroscopy and cyclic voltammetry. Ru(L)(PPh3)Cl-2 (1) has been characterized by X-ray diffraction. Structural features of (1) indicate a distorted octahedral coordination environment around the ruthenium(II) centre. The two chlorides are cis to each other with the Ru-Cl(1) bond trans to PPh3 longer than the Ru-Cl(2) bond. Several mixed-ligand complexes containing bipyridine, phenanthroline, 2-picolinate and oxalate were also isolated and the structure of one of the heterochelates has been solved. [Ru(L)(PPh3)(bpy)](ClO4)(2) (2) has also been structurally characterized. The structure and properties of (2) correspond to the predictions based on the structure of (1). (C) 1998 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(97)00520-2