3,5-bis(dicyclopentylphosphinomethyl)aniline-borane | 886989-07-7

• 英文名称: 3,5-bis(dicyclopentylphosphinomethyl)aniline-borane
• CAS: 886989-07-7
• 化学式: C₂₈H₅₁B₂NP₂
• 分子量: 485.289
• InChiKey: SKXFALSTUKSFFX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  苯酐 、 palladium(II) trifluoroacetate 、 3,5-bis(dicyclopentylphosphinomethyl)aniline-borane 以 甲苯 为溶剂， 以96%的产率得到4-phthalimido-2,6-bis(dicyclopentylphosphinomethyl)aniline-borane
  参考文献：
  名称：

  Synthesis and characterization of electronically varied XCX palladacycles with functional arene groups

  摘要：

  X-ray crystallographic studies show that varying the nature of the S-aryl ligands in SCS-Pd(II) pincer complexes and the electronic nature of the aryl substituent para to the Pd(II) group in PCP-Pd(II) pincer complexes do not lead to structural changes in these palladacycles that can be correlated with the changing nature of the ligands. While the original C2 symmetry for the S-aryl groups in SCS-Pd(H) pincer complexes seen in the case of the 2,5-bis(thiophenylmethyl)phenylpalladium chloride pincer complex is also seen in other SCS-Pd(II) pincer complexes, the relative stereochemistry of the S-aryl rings is not consistently maintained in 2,5-bis((4-dimethylaminothiophenyl)methyl)-phenylpalladium chloride. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2005.09.030
• 作为产物：
  描述：

  N-acetyl-3,5-bis(dicyclopentylphosphinomethyl)aniline-borane 在 盐酸 、 sodium hydroxide 作用下， 以 乙醇 为溶剂， 以58%的产率得到3,5-bis(dicyclopentylphosphinomethyl)aniline-borane
  参考文献：
  名称：

  Synthesis and characterization of electronically varied XCX palladacycles with functional arene groups

  摘要：

  X-ray crystallographic studies show that varying the nature of the S-aryl ligands in SCS-Pd(II) pincer complexes and the electronic nature of the aryl substituent para to the Pd(II) group in PCP-Pd(II) pincer complexes do not lead to structural changes in these palladacycles that can be correlated with the changing nature of the ligands. While the original C2 symmetry for the S-aryl groups in SCS-Pd(H) pincer complexes seen in the case of the 2,5-bis(thiophenylmethyl)phenylpalladium chloride pincer complex is also seen in other SCS-Pd(II) pincer complexes, the relative stereochemistry of the S-aryl rings is not consistently maintained in 2,5-bis((4-dimethylaminothiophenyl)methyl)-phenylpalladium chloride. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2005.09.030