[(cyclopentadienyl)Os(η2-C(=CHCH2CH2)CH2-C5H4N)(P(i-Pr)3)]PF6 | 1227063-90-2

• 英文名称: [(cyclopentadienyl)Os(η2-C(=CHCH2CH2)CH2-C5H4N)(P(i-Pr)3)]PF6
• CAS: 1227063-90-2
• 化学式: C₂₄H₃₇NOsP*F₆P
• 分子量: 705.702
• InChiKey: RUXPQFMODGXFMD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  [(cyclopentadienyl)Os(η2-C(CH2CH2CH2)=CH-C5H4N)(P(i-Pr)3)]PF6 以 fluorobenzene 为溶剂， 以80%的产率得到[(cyclopentadienyl)Os(η2-C(=CHCH2CH2)CH2-C5H4N)(P(i-Pr)3)]PF6
  参考文献：
  名称：

  Ring Expansion versus exo−endo Isomerization in (2-Pyridyl)methylenecyclobutane Coordinated to Hydrido(trispyrazolyl)borate- and Cyclopentadienyl-Osmium Complexes

  摘要：

  The reactions of (2-pyridyl)methylenecyclobutane with the metal fragments [OsTp((PPr3)-Pr-i)](+) and [OsCp((PPr3)-Pr-i)](+) (Tp = hydridotris(pyrazolyl)borate, Cp = cyclopentadienyl) are shown. Complex [OsTp(kappa(1)-OCMe2)(2)((PPr3)-Pr-i)]BF4 (1) reacts with the organic substrate to give [OsTp{eta(2)-C(CH2CH2CH2)=CH-C5H4N}((PPr3)-Pr-i)]BF4 (2), which evolves into the cyclopentylidene derivative [[OsTp(=CCH2CH2CH2CH-C5H4N)((PPr3)-Pr-i)]BF4 (3) as a result of the ring expansion of the methylenecyclobutane unit Idle coordinated substrate. The reaction of (2-pyridyl)methylenecyclobutane with [OsCp(NCCH3)(2)((PPr3)-Pr-i)]PF6 (4) leads to [OsCp{eta(2)-C(CH2CH2CH2)=CH-C5H4N}((PPr3)-Pr-i)]PF6 (5). In contrast to 2, complex 5 evolves by means of exo endo isomcrization of the C-C double bond of the coordinated substrate to afford [[OsCp(eta(2)-C(=CH2CH2CH2)-CH2-C5H4N)((PPr3)-Pr-i)]PF6 (6).

  DOI：

  10.1021/om100243w