dichlorobis(thiazole)iron(II) | 191218-69-6

• 英文名称: dichlorobis(thiazole)iron(II)
• CAS: 191218-69-6
• 化学式: C₆H₆Cl₂FeN₂S₂
• 分子量: 297.012
• InChiKey: WNCPCZJRWCUBJR-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  异噻唑 、 iron(II) chloride 以 乙醇 为溶剂， 生成 dichlorobis(thiazole)iron(II)
  参考文献：
  名称：

  Synthesis and crystal structure of the 1-dimensional dihalide-bridged polymers: dichlorobis(thiazole)iron(II) and dibromobis(thiazole)copper(II)

  摘要：

  The new polymeric compound Fe(thiazole)(2)Cl-2 (1) has been synthesised by the addition of thiazole to an ethanolic solution of anhydrous FeCl2. The structure of Cu(tz)(2)Br-2 (2) has also been determined. The structures of both polymers consist of pseudo-octahedral units, doubly linked by halide-bridges to form infinite linear chains. Slight variation in the bonding of the two are observed, relating to the Jahn-Teller nature of Cu2+. Room temperature magnetic susceptibility measurements of 1 give an effective moment of 5.51(2) B.M., indicating high-spin Fe(II). (C) 1998 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(97)00521-4

文献信息

• The metamagnetic behaviour of the one-dimensional dihalide-bridged polymer dichlorobis(thiazole)iron(II)
  作者：M. James

  DOI：10.1016/s0022-3697(00)00069-x

  日期：2000.11

  Abstract The magnetic properties for the polymeric compound Fe(thiazole) 2 Cl 2 ( 1 ) have been measured as a function of temperature and magnetic field. Variation of the magnetic field at 5 K between 0 and 10 kG reveals a metamagnetic transition between antiferromagnetic and ferromagnetic states. The low temperature magnetic susceptibilities have been fitted to a one-dimensional Ising model with a mean

  摘要 高分子化合物 Fe(thiazole) 2 Cl 2 ( 1 ) 的磁性已被测量为温度和磁场的函数。5 K 处的磁场在 0 到 10 kG 之间的变化揭示了反铁磁态和铁磁态之间的变磁转变。低温磁化率已被拟合到具有平均场校正的一维 Ising 模型，并且被发现具有高度各向异性，具有沿 b 轴的铁磁链内相互作用 (J ∥ /k=33.0(1) K ) 和较弱的反铁磁链间相互作用（z'J'/k=-0.3(1) K）。