mer-ruthenium(carbonyl)(ttp)I2 | 134535-00-5

• 英文名称: mer-ruthenium(carbonyl)(ttp)I2
• CAS: 134535-00-5
• 化学式: C₃₇H₃₇I₂OP₃Ru
• 分子量: 945.5
• InChiKey: PXAKPTRDQOCMAH-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  Ru(CO)2(bis(3-(diphenylphosphino)propyl)phenylphosphine) 在 I₂ 作用下， 以 苯 为溶剂， 以84%的产率得到mer-ruthenium(carbonyl)(ttp)I2
  参考文献：
  名称：

  Comparison of the reactions of Ru(CO)2(triphos) (triphos=etp, ttp and Cyttp) with I2 and CH3I

  摘要：

  The products of the reactions of I2 and CH3I with Ru(CO)2(triphos) (triphos = etp (PhP(CH2CH2PPh2)2), ttp (PhP(CH2CH2CH2PPh2)2) and Cyttp (PhP(CH2CH2CH2PCy2)2)) were characterized by P-31{H-1}, H-1, C-13{H-1} NMR and IR spectroscopy, and elemental analyses. The etp complex Ru(CO)2(etp) was prepared by treatment of Ru3(CO)12 with etp in refluxing benzene. fac-[RuX(CO)2(etp)I (X = I, Me) were produced when Ru(CO)2(etp) was treated with I2 and CH3I, respectively, either at room temperature or on refluxing. At room temperature, cis-mer-[RuI(CO)2(triphos)]I and [RuMe(CO)2(triphos)]I (triphos = ttp and Cyttp) were the products of the reaction of Ru(CO)2(triphos) with I2 and CH3I, respectively. The neutral complexes RuI2(CO)(triphos) (triphos = ttp and Cyttp) were synthesized by treatment of Ru(CO)2(triphos) with I2 in refluxing benzene.

  DOI：

  10.1016/s0020-1693(00)86781-x