[Re3(μ-Cl)3Cl2[OCMe(CF3)2]4(pyridine)] | 875538-48-0

• 英文名称: [Re3(μ-Cl)3Cl2[OCMe(CF3)2]4(pyridine)]
• CAS: 875538-48-0
• 化学式: C₂₁H₁₇Cl₅F₂₄NO₄Re₃
• 分子量: 1539.22
• InChiKey: MJVBQQOYKSFKCP-UHFFFAOYSA-I

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  吡啶 、 [Na(THF)2][Re3(μ-Cl)3Cl2[OCMe(CF3)2]5] 以 二氯甲烷 为溶剂， 以56%的产率得到[Re3(μ-Cl)3Cl2[OCMe(CF3)2]4(pyridine)2]
  参考文献：
  名称：

  Synthesis of fluoroalkoxide trirhenium(III) clusters

  摘要：

  The cluster Re-3(P-Cl)(3)Cl-6(THF)(3) reacted at room temperature in THF with 5 equivalents of NaOCMe(CF3)(2) to give [Na(THF)(2)][Re-3(mu-Cl)(3)Cl-2{OCMe(CF3)(2)}(5)]. The salt [Na(THF)(2)][Re-3(mu-Cl)(3)Cl-2{OCMe(CF3)(2)}(5)] reacted with a large excess of pyridine to produce Re-3(mu-Cl)(3)Cl-2[OCMe(CF3)(2)](4)(py)(2), which was isolated as a crystalline mixture of two isomers. The mono-pyridine adduct Re-3(mu-Cl)(3)Cl-2[OCMe(CF3)(2)](4)(py) was observed as a side product in reactions between the salt and pyridine. The mono-pyridine adduct Re-3(mu-Cl)(3)Cl-2[OCMe(CF3)(2)](4)(py) and one of the two isomers of the di-pyridine adduct Re-3(mu-Cl)(3)Cl-2[OCMe(CF3)(2)](4)(py)(2) were characterized by X-ray crystallography. The other isomer of Re-3(mu-Cl)(3)Cl-2[OCMe(CF3)(2)](4)(py)(2) and [Na(THF)(2)][Re-3(mu-Cl)(3)Cl-2{OCMe(CF3)(2)}(5)] were identified by X-ray crystallography but the structures were not fully refined. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2005.07.042