RuH(κ2-S2CNMe2)(CO)(PPh3)2 | 56800-88-5

• 英文名称: RuH(κ2-S2CNMe2)(CO)(PPh3)2
• CAS: 56800-88-5
• 化学式: C₄₀H₃₇NOP₂RuS₂
• 分子量: 774.889
• InChiKey: ITCRBVSETRSRMK-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  RuH(κ2-S2CNMe2)(CO)(PPh3)2 在 H₂S 、 CH₂Cl₂ 作用下， 以 苯 为溶剂， 以70%的产率得到
  参考文献：
  名称：

  具有巯基配体的单核和双核钌 (II) 化合物的合成和表征

  摘要：

  从硫化氢和[Ru(II)H(S2CNMe2)(CO)(PPh3)2]逐步合成具有巯基配体的单核和双核钌化合物。通过X射线晶体学确定分子结构。这些化合物对空气不稳定。

  DOI：

  10.1246/cl.1992.2389
• 作为产物：
  描述：

  在 KOH 作用下， 以 乙醇 为溶剂， 生成 RuH(κ2-S2CNMe2)(CO)(PPh3)2
  参考文献：
  名称：

  Hydroruthenation of prop-2-ynyltriphenylphosphonium bromide: synthesis, crystal structure and reactions of [RuBr(CHCHCH₂PPh3)(CO)(PPh₃)₂]PF₆

  摘要：

  复杂物[RuClH(CO)(PPh3)3]与丙-2-炔基三苯基膦溴化物([Ph3PCH2CCH]Br)反应，随后与NH4PF6反应，生成晶体学特征盐[RuBr(CHCHCH2PPh3)(CO)(PPh3)2]PF6。由于钌中心的配位不饱和，进一步发生了配体CNC6H3Me2-2,6和CO对Ru的加成，以及SO2对Ru-C σ键的插入。

  DOI：

  10.1039/c39950000369

文献信息

• Organometallic chemistry of ethynyl boronic acid MIDA ester, HCCB(O₂CCH₂)₂NMe
  作者：Anthony F. Hill、Craig D. Stewart、Jas S. Ward

  DOI：10.1039/c4dt03695f

  日期：——

  The reactions of HCCBMIDA (BMIDA = B(O₂CCH₂)₂NMe) with a range of ruthenium complexes examples of σ-alkynyl, σ-alkenyl and vinylidene complexes bearing 4-coordinate boron substituents.

  HCCBMIDA（BMIDA = B（O₂CCH₂）₂NMe）与一系列钌配合物反应的结果是形成了具有4配位硼取代基的σ-炔基、σ-烯基和乙烯基配合物的示例。
• The coupling of methylene and vinyl ligands at a ruthenium(II) centre
  作者：Anthony F. Hill、Chean T. Ho、James D. E. T. Wilton-Ely

  DOI：10.1039/a704157h

  日期：——

  The reaction of [Ru(CHCH2)Cl(CO)(PPh3)2] with diazomethane provides the allyl complex [Ru(η3-CH2CHCH2)Cl(CO)(PPh3)2] which is also the product of the reactions of [RuHCl(CO)(PPh3)3] with either allene or propyne and which reacts subsequently with NaS2CNMe2 to provide [RuH(S2CNMe2)(CO)(PPh3)2] and allene.

  Ru(CHCH2)Cl(CO)(PPh3)2]与重氮甲烷反应生成烯丙基络合物[Ru(η3-CH2CHCH2)Cl(CO)(PPh3)2]，它也是[RuHCl(CO)(PPh3)3]与烯丙基或丙炔反应的产物，随后与 NaS2CNMe2 反应生成[RuH(S2CNMe2)(CO)(PPh3)2]和烯丙基。
• Tethered silyl complexes from nucleophilic substitution reactions at the Si–Cl bond of the chloro(diphenyl)silyl ligand in Ru(SiClPh2)(κ2-S2CNMe2)(CO)(PPh3)2
  作者：Wai-Him Kwok、Guo-Liang Lu、Clifton E.F. Rickard、Warren R. Roper、L. James Wright

  DOI：10.1016/j.jorganchem.2004.06.031

  日期：2004.9

  Crystal structure determination of RuH(kappa(2)-S2CNMe2)(CO)(PPh3)(2) (1) confirms that the triphenylphosphine ligands are arranged mutually trans. 1 reacts readily with HSiClPh2 to eliminate H-2 and produce the six-coordinate silyl complex, Ru(SiClPh2)(kappa(2)- S2CNMe2)(CO)(PPh3)(2) (2). Crystal structure determination of 2 reveals the same geometrical arrangement of ligands as in 1 with the silyl ligand replacing the hydride ligand. The chloride bound to silicon in 2 is replaced through reactions with 2-hydroxypyridine, 2-aminopyridine, and thallium acetate, producing, respectively, the mono-PPh3 complexes, Ru(kappa(2)(Si,N)-SiPh2OC5H4N) (kappa(2-)S(2)CNMe(2))(CO)(PPh3) (3), Ru(kappa(2)(Si,N)-SiPh2NHC5H4N)(kappa(2)-S2CNMe2)(CO)PPh3) (4), and Ru(kappa(2)(Si,O)-SiPh2OCMeO)(kappa(2)-S2CNMe2)(CO)(PPh3) (5). Crystal structure determinations of 3, 4, and 5 confirm that in each case there is formation of a five-membered chelate ring tethering the silyl ligand to ruthenium. In the formation of 3, 4, and 5 the Si-ligand and the two S atoms of the dimethyldithiocarbamate ligand remain meridional but the remaining triphenylphosphine ligand and the carbonyl ligand are interchanged in position leaving the donor atom of the tether trans to the CO ligand. An alternative way of considering the tethered silyl ligands in 3, 4, and 5 is as tethered, base-stabilised, silylene ligands and the structural data give some support for a contribution from this bonding model. (C) 2004 Elsevier BN. All rights reserved.
• Uemura, Hiroyuki; Kawano, Masaki; Watanabe, Takehide, Inorganic Chemistry, 1992, vol. 31, # 24, p. 5137 - 5139
  作者：Uemura, Hiroyuki、Kawano, Masaki、Watanabe, Takehide、Matsumoto, Takaya、Matsumoto, Kazuko

  DOI：——

  日期：——
• Kawano, Masaki; Uemura, Hiroyuki; Watanabe, Takehide, Journal of the American Chemical Society, 1993, vol. 115, p. 2068 - 2070
  作者：Kawano, Masaki、Uemura, Hiroyuki、Watanabe, Takehide、Matsumoto, Kazuko

  DOI：——

  日期：——