[Ru(2-(4-tolyl)pyridine)(acetonitrile)4]PF6 | 388500-21-8

• 英文名称: [Ru(2-(4-tolyl)pyridine)(acetonitrile)4]PF6
• 英文别名: [Ru(o-2-(4-tolyl)pyridine-H)(MeCN)4]PF6；[Ru(o-4-MeC6H3-2-py)(MeCN)4]PF6
• CAS: 388500-21-8
• 化学式: C₂₀H₂₂N₅Ru*F₆P
• 分子量: 578.462
• InChiKey: GCCJSUBUABXSGU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  1,10-菲罗啉 、 [Ru(2-(4-tolyl)pyridine)(acetonitrile)4]PF6 以 甲醇 为溶剂， 以72%的产率得到[Ru(2-(4-tolyl)pyridine)(1,10-phenanthroline)2]PF6
  参考文献：
  名称：

  New Synthesis and New Bio-Application of Cyclometalated Ruthenium(II) Complexes for Fast Mediated Electron Transfer with Peroxidase and Glucose Oxidase

  摘要：

  DOI：

  10.1021/ic010423h
• 作为产物：
  描述：

  [RuCl2(benzene)]2 、 2-(4-甲基苯基)吡啶 以 not given 为溶剂， 生成 [Ru(2-(4-tolyl)pyridine)(acetonitrile)4]PF6
  参考文献：
  名称：

  Unusual phenomenon in the chemistry of orthometalated ruthenium (II) complexes

  摘要：

  Yellow cyclometalatated ruthenium (II) complexes [Ru(o-X-2-py)(MeCN)(4)1PF(6) (1, X = C6H4 (a) or 4-MeC6H3 (b)) react readily with 1,10-phenanthroline (LL) in MeCN to give brownish-red species cis-[Ru(o-X-2-py)(LL)(MeCN)(2)]PF6 in high yields. The same reaction of the same complexes under the same conditions with 2,2'-bipyridine results in a significant color change from yellow to brownish-orange suggesting a formation of new species. Surprisingly, X-ray structural studies of these two complexes showed that they are structurally indistinguishable from the starting complexes 1. Referred to as complexes 4a,b, the new compounds are slightly more stable in the air though their spectral characteristics in solution are similar to 1a,b. The diffuse reflectance spectroscopy is so far the only technique that indicated differences between I and 4. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2005.05.034