trans-[Rh(Cl)(2,6-dimethylphenyl isocyanide)(PPh3)2] | 148617-28-1

• 英文名称: trans-[Rh(Cl)(2,6-dimethylphenyl isocyanide)(PPh3)2]
• 英文别名: RhCl(2,6-dimethylphenylisocyanide)(PPh3)2
• CAS: 148617-28-1；80181-85-7
• 化学式: C₄₅H₃₉ClNP₂Rh
• 分子量: 794.117
• InChiKey: PZELJUILJGUBAD-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  Wilkinson's catalyst 以 二氯甲烷 为溶剂， 生成 trans-[Rh(Cl)(2,6-dimethylphenyl isocyanide)(PPh3)2]
  参考文献：
  名称：

  Influence of Ligand Polarizability on the Reversible Binding of O₂ by trans-[Rh(X)(XNC)(PPh₃)₂] (X = Cl, Br, SC₆F₅, C₂Ph; XNC = Xylyl Isocyanide). Structures and a Kinetic Study

  摘要：

  The complexes trans-[Rh(X)(XNC)(PPh3)(2)] (X = Cl, 1; Br, 2; SC6F5, 3; C2Ph, 4; XNC = xylyl isocyanide) combine reversibly with molecular oxygen to give [Rh(X)(O-2)(XNC)(PPh3)(2)] of which [Rh(SC6F5)(O-2)(XNC)(PPh3)(2)] (7) and [Rh(C2Ph)(O-2)(XNC)(PPh3)(2)] (8) are sufficiently stable to be isolated in crystalline form. Complexes 2, 3, 4, and 7 have been structurally characterized. Kinetic data for the dissociation of O-2 from the dioxygen adducts of 1-4 were obtained using P-31 NMR to monitor changes in the concentration of [Rh(X)(O-2)(XNC)(PPh3)(2)] (X = Cl, Br, SC6F5, C2Ph) resulting from the bubbling of argon through the respective warmed solutions (solvent chlorobenzene). From data recorded at temperatures in the range 30-70 degrees C, activation parameters were obtained as follows: Delta H double dagger (kJ mol(-1)): 31.7 +/- 1.6 (X = Cl), 52.1 +/- 4.3 (X = Br), 66.0 +/- 15.8 (X = SC6F5), 101.3 +/- 1.8 (X = C2Ph); Delta S double dagger (J K-1 mol(-1)): -170.3 +/- 5.0 (X = Cl), -120 +/- 13.6 (X = Br), -89 +/- 18.2 (X = SC6F5), -6.4 +/- 5.4 (X = C2Ph). The values of Delta H double dagger and Delta S double dagger are closely correlated (R-2 = 0.9997), consistent with a common dissociation pathway along which the rate-determining step occurs at a different position for each X. Relative magnitudes of Delta H double dagger are interpreted in terms of differing polarizabilities of ligands X.

  DOI：

  10.1021/ic800478g

文献信息

• The catalytic substitution of metal carbonyls and substituted metal carbonyls by isonitriles in the presence of rhodium(I) and polymer-supported rhodium(I) complexes
  作者：Michel O. Albers、Neil J. Coville、Christakis P. Nicolaides、Ronald A. Webber、Terence V. Ashworth、Eric Singleton

  DOI：10.1016/s0022-328x(00)85787-3

  日期：1981.9

  Metal carbonyls and substituted metal carbonyls, under relatively mild reaction conditions, in the presence of isonitriles, undergo catalytic CO substitution by rhodium(I) and polymer-supported rhodium(I) complexes. The reaction provides a facile route to the synthesis of transition metal isonitrile metal isonitrile complexes.

  在相对温和的反应条件下，在异腈存在下，羰基金属和取代的羰基金属通过铑（I）和聚合物负载的铑（I）配合物进行催化CO取代。该反应提供了合成过渡金属异腈金属异腈配合物的简便途径。
• Baker, R. Thomas; Calabrese, Joseph C.; Westcott, Stephen A., Journal of the American Chemical Society, 1993, vol. 115, # 10, p. 4367 - 4368
  作者：Baker, R. Thomas、Calabrese, Joseph C.、Westcott, Stephen A.、Nguyen, Paul、Marder, Todd B.

  DOI：——

  日期：——