| 1450889-99-2

• CAS: 1450889-99-2
• 化学式: C₂₀H₂₁CdCl₂FeN₃O₃
• 分子量: 590.568
• InChiKey: JBJZVVJRCWHPOQ-OSHHITGSSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  水 、 anti-β-ferrocenylethylamino p-chlorophenylglyoxime 、 aqueous cadmium chloride 在 sodium hydroxide 作用下， 以 乙醇 为溶剂， 反应 0.5h， 以46%的产率得到
  参考文献：
  名称：

  Synthesis, spectroscopic, and cyclic voltammetric studies of ferrocene containing vic-dioxime ligand and its complexes with Ni(II), Cu(II), Co(II), Cd(II) and Zn(II)

  摘要：

  A vic-dioxime ligand containing the ferrocene group anti-beta-ferrocenylethylamino p-chlorophenylglyoxime (I) was synthesized from the reaction of beta-ferrocenylethylamine with anti-chloro-p-chlorophenylglyoxime. The mononuclear Ni(II), Cu(II), Co(II), Zn(II), and Cd(II) complexes of the vic-dioxime ligand were prepared and characterized using elemental analyses, mass spectra, Fourier transform infrared spectroscopy (FT-IR), UV-Vis spectroscopy (UV-Vis), magnetic susceptibility, nuclear magnetic resonance spectroscopy (H-1 NMR, and C-13 NMR) techniques. The redox behavior was studied using cyclic voltammetry and revealed metal-centered reduction processes for all complexes. (C) 2013 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2013.06.012