[Ir(ppz)2(4,7-di(1H-indol-1-yl)-1,10-phenanthroline)][PF6] | 1384272-74-5

• 英文名称: [Ir(ppz)2(4,7-di(1H-indol-1-yl)-1,10-phenanthroline)][PF6]
• CAS: 1384272-74-5
• 化学式: C₄₆H₃₂IrN₈*F₆P
• 分子量: 1034.0
• InChiKey: CMXZUOIVJCXRIR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  六氟磷酸钾 、 chloro(1-phenylpyrazole)iridium(III) dimer 、 4,7-bis-(1H-indole-1-yl)-1,10-phenanthroline 以 甲醇 、 二氯甲烷 为溶剂， 以65%的产率得到[Ir(ppz)2(4,7-di(1H-indol-1-yl)-1,10-phenanthroline)][PF6]
  参考文献：
  名称：

  Synthesis, structure and photophysical properties of cationic Ir(III) complexes with functionalized 1,10-phenanthroline ancillary ligands

  摘要：

  A series of substituted phenanthroline ancillary ligands with different degrees of steric hindrance, namely, 4,7-di(1H-pyrrol-1-yl)-1,10-phenanthroline (L1), 4,7-di(1H-indol-1-yl)-1,10-phenanthroline (L2) and 4,7-di(9H-carbazol-9-yl)-1,10-phenanthroline (L3), were synthesized in order to prepare cationic Ir(III) complexes. The results of photophysical studies revealed that functionalization with higher degree of steric hindrance L3 led to significant improvement of photoluminescence quantum yields (PLQYs) in neat film for these Ir(III) complexes, which may be attributed to the decrease of the intermolecular interactions. The mechanism of photophysical properties were rationalized with the help of quantum chemical calculations. Moreover, the complexes with L3 as ancillary ligands possessed good thermal stability, indicating their potential application as candidate for light-emitting electrochemical cells (LECs). (C) 2012 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2012.04.018