(Ru3(CO)11)2(μ-bis(diphenylphosphino)butadiyne) | 150086-08-1

• 英文名称: (Ru3(CO)11)2(μ-bis(diphenylphosphino)butadiyne)
• CAS: 150086-08-1
• 化学式: C₅₀H₂₀O₂₂P₂Ru₆
• 分子量: 1641.06
• InChiKey: KGWLBUQIYPLCKE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  (Ru3(CO)11)2(μ-bis(diphenylphosphino)butadiyne) 以 二氯甲烷 为溶剂， 以73%的产率得到(Ru3(μ-PPh2)(CO)9)2(μ3:μ3-C4)
  参考文献：
  名称：

  含有四碳（C 4）配体的络合物的新途径

  摘要：

  {Ru组成的溶液的热解3（CO）11 } 2（μ-BDPP）（BDPP =双（二苯基膦基）丁二炔），产生复杂的{茹3（μ-PPH 2）（CO）9 } 2（μ 6 - ç 4），其中包含一个μ 6 -C 4配体对称地桥接两个孺3（μ-PPH 2）（CO）9簇。当在Fe 2（CO）9存在下加热络合物{Fe（CO）4 } 2（μ-bdpp）时，C 4络合物的另一个实例为{Fe 2（μ-PPH 2）（CO）6 } 2（μ-C 4），获得。两种配合物均通过X射线结构测定来表征。C 4配体表现为buta-1,3-diyne-1,4-diyl系统。

  DOI：

  10.1016/0022-328x(93)80170-g
• 作为产物：
  描述：

  Ru3(CO)11(acetonitrile) 以 二氯甲烷 、 乙腈 为溶剂， 生成 (Ru3(CO)11)2(μ-bis(diphenylphosphino)butadiyne)
  参考文献：
  名称：

  Cluster chemistry. Part 91. Clusters derived from 1,4-Bis (diphenylphosphino)buta-1,3-diyne and their pyrolysis products: a route to complexes containing the tetracarbon ligand

  摘要：

  Reactions of (Mn(CO)11(NCMe)] (M(n) = Ru3, Os3, Re3(mu-H)3, or Ru4(mu-H4)4] with the linear bis(phosphine) PPh2C2C2PPh2(bdpp) afford the 'barbell' complexes [{Mn(CO)11}2(mu-bdpp)] [M(n) = Ru3 1 (38), Os3 2 (68), Re3(mu-H), 4 (44), or Ru4(mu-H)4 6 (39%)]. The monosubstituted complexes [Mn(CO)11(bdpp)] [M(n) = Os3 or Re3(mu-H)3 5] were isolated when an excess of bdpp was used. Reactions of 3 with [M3(CO)11(NCMe)] [M3 = Ru3 or Re3(mu-H)3] afforded the mixed-metal complexes [{Os3(CO)11}(mu-bdpp){M3(CO)11}] [M3 = Ru 7 (40) or Re3(mu-H)3 8 (63%)]. In a similar fashion [{Re3(mu-H)3(CO)11)(mu-bdpp){Ru3(CO)11}] 9 was prepared (38%) from 5 and [Ru3(CO)11(NCMe)]. When a solution of 1 in CH2Cl2 was gently heated under a nitrogen purge the C4 complex [{Ru3(mu-PPh2)(CO)9}2(mu3:mu3-C4)] 10 was produced in 73% yield. Without purging, the yield is much reduced; a minor product from the reaction is [{Ru4(mu-H)(CO)12}{mu4-PPh(C6H4)C2C2PPh2}{Ru3(CO)11}] 11. Complex 11 contains an Ru3(CO)11 moiety linked via a PPh2C2C2PPh(C6H4) ligand to an Ru3-spiked RU3 Cluster. One of the C2 units is attached in a mu-sigma,sigma,eta2-vinylic mode to the spike Ru and to two of the three Ru atoms in the closed triangular core. When 11 was recrystallised from CH2Cl2-MeOH the complex [{Ru4(mu3-OMe)(mu-PPh2)(CO)10}{mu4-CCH-mu-eta2-C2){RU2(mu-PPh2)(CO)6}] 12 was formed. This complex contains an Ru4 rhombus, opposite faces of which carry mu3-OMe and a mu4-vinylidene ligand; the latter is attached via a C-C single bond to the binuclear fragment. The complex [{Os3(mu-PPh2)(CO)9}2(mu3:mu3-C4)] 13 was obtained (78%) by pyrolysis of 2 in refluxing toluene. The structures of complexes 6 and 10-13 were determined by single-crystal X-ray studies.

  DOI：

  10.1039/dt9930003299

文献信息

• Cluster chemistry. Part 92. Directed syntheses and crystal structures of [{Ru₃(CO)₁₁}{µ-PPh₂[C₂CO₂(CO)₆]C₂}{Ru₂-(µ-PPh₂)(CO)₆}]·CH₂Cl₂, [{Os₃(CO)₁₁}(µ-PPh₂C₂C₂){Co₂Os₃-(µ-PPh₂)(CO)₁₃}] and [Co₂Os₃Re{µ₆-C₂Cch (PPh₂)}-(µ-PPh₂)(µ-CO)₂(CO)₁₄·CH₂Cl₂
  作者：Chris J. Adams、Michael I. Bruce、Ernst Horn、Brian W. Skelton、Edward R. T. Tiekink、Allan H. White

  DOI：10.1039/dt9930003313

  日期：——

  [Co2(CO)8] with [Mn(CO)11}2(µ-bdpp)][Mn Ru3, Os3, Re3(µ-H)3 or Ru4(µ-H)4; bdpp PPh2C2C2PPh2] afforded [Mn(CO)11}2µ-PPh2[C2Co2(CO)6]C2 PPh2}][Mn Ru31, Os32, Re3(µ-H)33 or Ru4(µ-H)44] in which the Co2(CO)6 moiety bonds to one of the CC triple bonds of the bridging bdpp ligand. Pyrolysis of 1 yielded [Ru3(CO)11}µ-PPh2[C2Co2(CO)6]C2}Ru2(µ-PPh2)(CO)6}]5, which is formed by concomitant addition of a

  [CO的反应2（CO）8与[M] Ñ（CO）11 } 2（μ-BDPP）] [M Ñ茹3，锇3中，Re 3（μ-H）3或Ru 4（μ- H）4 ; bDPP PPh 2 C 2 C 2 PPh 2 ]得到[M n（CO）11 } 2 µ-PPh 2 [C 2 Co 2（CO）6 ] C 2 PPh 2 }] [M nRu 3 1，Os 3 2，Re 3（µ-H）3 3或Ru 4（µ-H）4 4 ]，其中Co 2（CO）6部分键合至桥接的C C三键之一bDPP配体。1的热解生成[Ru 3（CO）11 } µ-PPh 2 [C 2 Co 2（CO）6 ] C 2 } Ru 2（µ-PPh 2）（CO）6 }] 5，这是通过在一个Ru 3簇上同时添加P–C（sp）键和消除Ru（CO）4片段而形成的。在通过加热2获得的[Os 3（CO）11 }（µ-PPh 2 C 2 C 2）Co