2-phenyl-1,3,2-diazaphospha-[3]ferrocenophane | 767334-51-0

• 英文名称: 2-phenyl-1,3,2-diazaphospha-[3]ferrocenophane
• CAS: 767334-51-0
• 化学式: C₁₆H₁₅FeN₂P
• 分子量: 322.129
• InChiKey: QMHVKAROSPQWBG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  2-phenyl-1,3,2-diazaphospha-[3]ferrocenophane 、 sulfur 以 二氯甲烷 为溶剂， 以95%的产率得到2-tert-butyl-1,3,2-diaza-thiophosphoryl-[3]ferrocenophane
  参考文献：
  名称：

  The first 1,3,2-diazaphospha-[3]ferrocenophanes

  摘要：

  1,1'-Diaminoferrocene 1 reacts with tert-butyl-(2a) and phenylphosphorus dichloride (2b) in the presence of triethylamine to afford the respective 1,3,2-diazaphospha-[3]ferrocenophanes 3a and 3b, of which 3a could be isolated in good yield and high purity. The phosphane 3a reacts with bis(trimethylsilyl)peroxide to give the oxide 5a, and with sulfur and selenium to the sulfide (6a) and the selenide (7a), respectively. The molecular structures of 3a and 7a, as determined by X-ray analysis, show that the tert-butyl group is in cis-position relative to the N-H bond vectors. NMR spectra prove that prominent structural features are retained in solution. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2004.04.026
• 作为产物：
  描述：

  1,1'-ferrocene diamine 、 苯基二氯化磷 在 Et₃N 作用下， 以 乙醚 为溶剂， 生成 2-phenyl-1,3,2-diazaphospha-[3]ferrocenophane 、
  参考文献：
  名称：

  The first 1,3,2-diazaphospha-[3]ferrocenophanes

  摘要：

  1,1'-Diaminoferrocene 1 reacts with tert-butyl-(2a) and phenylphosphorus dichloride (2b) in the presence of triethylamine to afford the respective 1,3,2-diazaphospha-[3]ferrocenophanes 3a and 3b, of which 3a could be isolated in good yield and high purity. The phosphane 3a reacts with bis(trimethylsilyl)peroxide to give the oxide 5a, and with sulfur and selenium to the sulfide (6a) and the selenide (7a), respectively. The molecular structures of 3a and 7a, as determined by X-ray analysis, show that the tert-butyl group is in cis-position relative to the N-H bond vectors. NMR spectra prove that prominent structural features are retained in solution. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2004.04.026