[Cu2(2,2':4',4'':2'',2'''-quaterpyridyl-6',6''-di-2-pyridine)Br4] | 622829-04-3

• 英文名称: [Cu2(2,2':4',4'':2'',2'''-quaterpyridyl-6',6''-di-2-pyridine)Br4]
• 英文别名: [Cu2(bisterpy)Br4]
• CAS: 622829-04-3
• 化学式: C₃₀H₂₀Br₄Cu₂N₆
• 分子量: 911.237
• InChiKey: VRQACXIGJLVWKF-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  4-[2,6-二(2-吡啶基)-4-吡啶基]-2,6-二(2-吡啶基)吡啶 、 copper(ll) bromide 以 水 为溶剂， 以80%的产率得到[Cu2(2,2':4',4'':2'',2'''-quaterpyridyl-6',6''-di-2-pyridine)Br4]
  参考文献：
  名称：

  Anion influences on the construction of one-dimensional structures of the Cu(II)–bisterpy family (bisterpy=2,2′:4′,4″:2″,2‴-quarterpyridyl, 6′,6″-di-2-pyridiine)

  摘要：

  The hydrothermal reactions of M(II) salts with 2,2':4',4":2",2"'-quaterpyridyl, 6,6"-di-2-pyridine (bisterpy) in the presence of a variety of anionic subunits have been investigated. The compounds [Cu-2(bisterpy)(H2O)(2)Cl-2]Cl-2 (1), [Cu-2(bisterpy)Br-4] (2), and [Cu-2(bisterpy) (NO3)(4)] . 2H(2)O (3 . 2H(2)O) are molecular. In contrast, [Cu-2(bisterpy)Cl-2(PF6)] (4), [Mn-2(bisterpy)(SO4)(2)] (5), [Zn-2(bisterpy)(SO4)(2)] (6), [Cu-2(phbisterpy)(SO4)(2)] . 2H(2)O (7 . 2H(2)O), [Cu-2(bisterpy)(MoO4)(2)] (8), [Zn-2(bisterpy)(MoO4)(2)] (9) [Cu-2(bisterpy)(H2O)(2)(SO4)] [Mo4O13] . 1.25H(2)O (10 . 1.25H(2)O) and [Cu-2(bisterpy)Mo8O26] . 2H(2)O (11-2H(2)O) are one-dimensional materials. The structural evolution of the molybdate series 8, 10, and 11 illustrates the profound influence of hydrothermal reaction conditions on product identity and architecture. The (PF6)(-) bridged solid 4 is mixed valence Cu(I)/Cu(II), a feature consistent with the magnetic properties of this material. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(03)00186-5