N-[4-ferrocenyl-2-methyl-4-oxobut-1-enyl]-N'-phenylthiourea | 1340588-41-1

• 英文名称: N-[4-ferrocenyl-2-methyl-4-oxobut-1-enyl]-N'-phenylthiourea
• CAS: 1340588-41-1
• 化学式: C₂₇H₂₅FeN₃OS
• 分子量: 495.428
• InChiKey: HVNAGDGKOYXWPK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  1-ferrocenyl-1,3-butanedione 、 N-(2-氨基苯基)-N-苯基硫脲 以 乙醇 为溶剂， 以72%的产率得到N-[4-ferrocenyl-2-methyl-4-oxobut-1-enyl]-N'-phenylthiourea
  参考文献：
  名称：

  Dual chemosensing properties of new ferrocene-based receptors towards fluoride and copper(II) ions

  摘要：

  The new ferrocene based receptors N-[4-ferrocenyl-2-methyl-4-oxobut-1-enyl]-N'-phenylthiourea (1), N-[4-ferrocenyl-2-methyl-4-oxobut-1-enyl]-N'-[4-nitrophenyl]thiourea (2) were synthesized and characterized. Fluorescence titrations of receptors 1 and 2 with various transition metal ions showed selective response to Cu2+ ions and the emission intensities quenched significantly. Electrochemical titrations with anions revealed that receptors 1 and 2 sensed the F- anion in high selectivity with a cathodic shift of 100 mV. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2011.06.016