cis-dichloro-trans-bis(3,5-dimethylpyridine)(1,3-diphenyltriazenido)indium(III) | 143672-23-5

• 英文名称: cis-dichloro-trans-bis(3,5-dimethylpyridine)(1,3-diphenyltriazenido)indium(III)
• CAS: 143672-23-5
• 化学式: C₂₆H₂₈Cl₂InN₅
• 分子量: 596.268
• InChiKey: YWDQMORWPBBNME-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  3,5-二甲基吡啶 、 tetraethylammonium cis-dichlorobis(1,3-diphenyltriazenido)indate(III) 在 CF₃CO₂H 作用下， 以 not given 为溶剂， 以90%的产率得到cis-dichloro-trans-bis(3,5-dimethylpyridine)(1,3-diphenyltriazenido)indium(III)
  参考文献：
  名称：

  Indium complexes of 1,3-diphenyltriazene

  摘要：

  The reaction of InCl3 with 1,3-diphenyltriazene (Hdpt) in the presence of NEt3 gives the six-co-ordinate indium complex [NHEt3][InCl2(dPt)2] 1a. The interaction of 1a with [NEt4]Cl and [N(PPh3)2]Cl allows for the isolation of the appropriate salts, [NEt4][InCl2(dPt)2] 1b and [N(PPh3)2][InCl2(dpt)2] 1c. Reaction of Lewis bases, L, with 1a yields [InCl2(dpt)L2], L = pyridine 2, 3,5-dimethylpyridine 3, PEt3 4, L2 = 2,2'-bipyridine 5, 1,10-phenanthroline 6, Me2PCH2CH2PMe2 7 or Et2PCH2CH2PEt2 8. The mechanism for these reactions is discussed. No reaction is observed between 1b and 3,5-dimethylpyridine. The X-ray structures of 1a, 3, 4 and 5 have been determined. Compounds 2-4 are readily soluble in aromatic hydrocarbon solvents, while 5-8 are insoluble as a consequence of the presence of a supramolecular architecture involving dipolar In-Cl ... N interactions in the solid state. All new compounds have been characterised by H-1, C-13-{H-1} and P-31-{H-1} NMR and IR spectroscopy.

  DOI：

  10.1039/dt9920002183