| 1323440-28-3

• CAS: 1323440-28-3
• 化学式: C₂₉H₃₆Cl₂N₄Rh₂
• 分子量: 717.349
• InChiKey: YHEXPELCRMYZOY-XTSSNGSKSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2-imidazol1-yl-5,7-dimethyl-1,8-naphthyridine 、 chloro(1,5-cyclooctadiene)rhodium(I) dimer 以 二氯甲烷 为溶剂， 以91%的产率得到
  参考文献：
  名称：

  Naphthyridine–imidazole hybrid ligands for the construction of multinuclear architecture

  摘要：

  Reaction of 2-imidazolyl-5,7-dimethyl-1,8-naphthyridine (L(1)) with [Rh(COD) Cl](2) (COD = 1,5-cyclooctadiene) affords the dinuclear complex [Rh(COD)Cl](2)(mu-L(1)) (1). Elimination of chloride from the metal coordination sphere leads to a self-assembled tetranuclear macrocycle [Rh(COD)L(1)](4)[ClO(4)](4) (2). A subtle alteration in the ligand framework results in the polymeric chain compound {Rh(COD)(L(2))}(n)(PF(6))(n) (3) (L(2) = 2-imidazolyl-3-phenyl-1,8-naphthyridine). In all these complexes, the imidazole nitrogen and one of the naphthyridine nitrogen (away from the imidazole substituent) bind the metal. The 'parallel' and 'perpendicular' dispositions of nitrogens are observed in these compounds contributing to different Rh center dot center dot center dot Rh separations. The L(1) ligand adopts planar configuration, whereas the naphthyridine-imidazole rings deviate from planarity in L(2) yielding a polymeric structure. The extent of deviation is less in the polymeric structure {Mo(2)(OAc)(4)(L(2))}(n) (4) in which the ligand exhibits weak axial interactions to the metal. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2011.03.033