[Ag(ClO4)(1,4-bis(diphenylphosphino)butane)]2 | 844842-36-0

• 英文名称: [Ag(ClO4)(1,4-bis(diphenylphosphino)butane)]2
• 英文别名: [Ag(ClO4)(dppb)]2
• CAS: 844842-36-0
• 化学式: C₅₆H₅₆Ag₂Cl₂O₈P₄
• 分子量: 1267.59
• InChiKey: FGIVISRAWXTRIU-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  silver perchlorate 、 1,4-双(二苯基膦)丁烷 以 乙腈 为溶剂， 以84%的产率得到[Ag(ClO4)(1,4-bis(diphenylphosphino)butane)]2
  参考文献：
  名称：

  The structural definition of adducts of stoichiometry MX:dppx (1:1) M=CuI, AgI, X=simple anion, dppx=Ph2P(CH2)xPPh2, x=3–6

  摘要：

  Single crystal X-ray structural characterizations are recorded for a wide range of adducts of the form MX:dppx (1:1)((n)), M = silver(I) (predominantly), copper(I), X = simple (pseudo-) halide or oxy-anion (the latter spanning, where accessible, perchlorate, nitrate, carboxylate - a range of increasing basicity), dppx=bis(diphenylphosphino)alkane, Ph2P(CH2)(x)PPh2, x = 3-6. Adducts are defined of two binuclear forms: (i) [LM(mu-X)(2)L], with each ligand chelating a single metal atom, and (ii) [M(mu-X)(2)(mu-(P-L-P'))(2)M'] where both ligands L and halides bridge the two metal atoms; a few adducts Lire defined as polymers, the ligands connecting M(p-X)2M' kernels, this motif persisting in all forms. Synthetic procedures for all adducts have been reported. All compounds have been characterized both in solution (H-1, C-13, P-31 NMR, ESI MS) and in the solid state (IR). (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2004.09.047