Ru(TTP)(CO)(ppyr)Pd(Me)Cl | 1551161-48-8

• 英文名称: Ru(TTP)(CO)(ppyr)Pd(Me)Cl
• 英文别名: Ru(tetratolylporphyrin)(CO)(2-(pyrid-2-yl)pyrazine)Pd(Me)Cl
• CAS: 1551161-48-8
• 化学式: C₅₉H₄₆ClN₇OPdRu
• 分子量: 1112.0
• InChiKey: OQTCXZZSOBAOSV-BKMDVBMKSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  chloromethyl(1,5-cyclooctadiene)palladium(II) 、 Ru(TTP)(CO)(ppyr) 在 air 作用下， 以 二氯甲烷 为溶剂， 反应 2.0h， 生成 Ru(TTP)(CO)(ppyr)Pd(Me)Cl 、 Ru(TTP)(CO)(ppyr)Pd(Me)Cl
  参考文献：
  名称：

  Synthesis of trinuclear Pd–Ru–Pd porphyrin complexes with axially ligated Pd centers. Prominent metal-to-ligand charge transfer band in the visible region

  摘要：

  Ru-porphyrin complexes with pyridylpyrazine as metal coordination sites were synthesized. Introduction of Pd-alkyl units to the binding site led to the formation of a novel Pd-Ru-Pd trinuclear complex. The metalation causes drastic changes in the electrochemical and photophysical properties. The trinuclear complex exhibited a prominent metal-to-axial ligand charge transfer band in the visible region due to small energy gap between the Ru-based HOMO and the axial ligand-based LUMO. These changes resulted in the drastic color change from orange to green. (C) 2013 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2013.12.008