(2-tolylpyridine)PtCl(2-trifluoromethylpyridine) | 1356925-69-3

• 英文名称: (2-tolylpyridine)PtCl(2-trifluoromethylpyridine)
• CAS: 1356925-69-3
• 化学式: C₁₈H₁₄ClF₃N₂Pt
• 分子量: 545.851
• InChiKey: XRUNVXWXHHRGQN-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  2-(4-甲基苯基)吡啶 以 乙醇 、 氯仿 、 水 为溶剂， 生成 (2-tolylpyridine)PtCl(2-trifluoromethylpyridine)
  参考文献：
  名称：

  Mononuclear cycloplatinated complexes derived from 2-tolylpyridine with N-donor ligands: Reactivity and structural characterization

  摘要：

  The cycloplatinated dichloro-bridged complex [(2-Tolpy)Pt(mu-Cl)12 (1), obtained by treatment of 2-tolylpyridine with K2PtCl4, reacts with different N-donor ligands in a 1:2 molar ratio in chloroform to give the corresponding mononuclear complexes [(2-Tolpy)Pt(L)Cl] [L = pyridine (2), 2-trifluoromethylpyridine (3), 3-trifluoromethylpyridine (4), 4-trifluoromethylpyridine (5), 2,6-dibromopyridine (6), 2-tolylpyridine (7) and morpholine (8)]. Compounds 2-5 and 8 exist as a single isomer in solution which show a trans-C,Cl geometry. In the case of compounds 6 and 7 a mixture of two isomers (trans-C,Cl and trans-C,L) was obtained and its relative ratio depends on the temperature. The crystal and molecular structures of compounds 5 and 7 were determined by X-ray crystallography. (C) 2011 Published by Elsevier Ltd.

  DOI：

  10.1016/j.poly.2011.11.055