dichlorozirconium[η2-C(N-2,6-dimethylphenyl)N(Me)cyclohexyl]2 | 610786-41-9

• 英文名称: dichlorozirconium[η2-C(N-2,6-dimethylphenyl)N(Me)cyclohexyl]2
• CAS: 610786-41-9
• 化学式: C₃₂H₄₆Cl₂N₄Zr
• 分子量: 648.874
• InChiKey: PAORZWADYVHPTN-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  2,6-二甲基苯基异腈 以 乙醚 、 正己烷 为溶剂， 生成 dichlorozirconium[η2-C(N-2,6-dimethylphenyl)N(Me)cyclohexyl]2
  参考文献：
  名称：

  New η²-Formamidinyl Zirconium Complexes:  Synthesis, Characterization, and Catalytic Activity

  摘要：

  The new eta(2)-formamidinyl Zr complex Zr(NMeCyc)(2)[C(NAr)NMeCyc](2) (1) (Ar = 2,6-dimethylphenyl, Cyc = cyclohexyl) was prepared upon double insertion of 2,6-dimethyl phenyl isocyanide in the Zr-N bond of Zr(NMeCyc)(4). 1 was then converted into Zr(OC6F5)(2)[C(NAr)N-MeCyc](2) (2) and ZrCl2[C(NAr)NMeCyc](2) (3) by reacting it with C6F5OH and [NHMe3]Cl, respectively. The crystal structure of 1 was established by X-ray analysis. All the complexes have been tested as catalysts for the polymerization of ethylene and 1-hexene in the presence of [NHMe2Ph][B(C6F5)(4)] as cocatalyst.

  DOI：

  10.1021/om030268+