σ-Pt[(η(5)-C5H3CMe=NC6H4Me-4)Fe(η(5)-C5H5)](DMSO)Cl | 192820-47-6

• 英文名称: σ-Pt[(η(5)-C5H3CMe=NC6H4Me-4)Fe(η(5)-C5H5)](DMSO)Cl
• CAS: 192820-47-6
• 化学式: C₂₁H₂₄ClFeNOPtS
• 分子量: 624.874
• InChiKey: LXHAJRUFZWNGIZ-HGLRXLPXSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  trans-PtCl2(DMSO)[(η(5)-C5H4CMe=NC6H4Me-4)Fe(η(5)-C5H5)] 在 NaOAc 作用下， 以 甲醇 、 甲苯 为溶剂， 以37%的产率得到σ-Pt[(η(5)-C5H3CMe=NC6H4Me-4)Fe(η(5)-C5H5)](DMSO)Cl
  参考文献：
  名称：

  Synthesis, characterization and structure of ferrocenylketimine complexes of platinum(II)

  摘要：

  The reactions of ferrocenylketimines [(eta(5)-C5H4CMe=NAr)Fe(eta(5)-C5H5)] (Ar=a variety of substituted phenyls) with cis-Pt(DMSO)(2)Cl-2 in refluxing toluene have led to the formation of both the five-membered cycloplatinated derivatives [sigma-Pt{(eta(5)-C5H4CMe=NAr)Fe(eta(5)-C5H5)}(DMSO)Cl] in the presence of sodium acetate and the coordinated compounds [trans-PtCl2(DMSO){(eta(5)-C5H4CMe=NAr)Fe(eta(5)-C5H5)}] in the absence of sodium acetate. The compounds have been characterized by elemental analysis, IR, H-1 NMR and two-dimensional NOESY spectra. The X-ray crystal structures of [sigma-Pt{(eta(5)-C5H3CMe=NPh)Fe(eta(5)-C5H5)}(DMSO)Cl] and [trans-PtCl2(DMSO){(eta(5)-C5H4CMe=NPh)Fe(eta(5)-C5H5)}] have been determined. (C) 1997 Elsevier Science S.A

  DOI：

  10.1016/s0022-328x(96)06948-3