| 1145662-04-9

• CAS: 1145662-04-9
• 化学式: C₄₈H₄₈N₆Rh₂
• 分子量: 914.76
• InChiKey: MSBZFEIWVDYUFF-GBBOUEDWSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  4-phenyl-5-(1-phenylvinyl)-2H-1,2,3-triazole 、 chloro(1,5-cyclooctadiene)rhodium(I) dimer 在 氢氧化钾 作用下， 以 甲醇 为溶剂， 以95%的产率得到
  参考文献：
  名称：

  Synthesis and Characterization of NH-triazole-Bound Rhodium(I) Complexes: Substituted-Group-Controlled Regioselective Coordination

  摘要：

  4,5-Disubstituted NH-1,2,3-triazoles (TRIA) were used to coordinate with Rh(I) metal cation, forming a new class of triazole-bridged [Rh(COD)(TRIA)](2) complexes in near-quantitative yields. X-ray crystallography studies revealed that the C-4-substituted groups effectively controlled the triazole binding sites, resulting in different coordination patterns. In addition, these air- and moisture-stable [Rh(COD)(TRIA)](2) complexes showed affective catalytic properties in Pauson-Khand reactions, with superior stability.

  DOI：

  10.1021/om8011163