diphenyl[2-(furan-2-ylmethylamino)methylferrocen-1-yl]stibine | 1167989-23-2

• 英文名称: diphenyl[2-(furan-2-ylmethylamino)methylferrocen-1-yl]stibine
• CAS: 1167989-23-2
• 化学式: C₂₈H₂₆FeNOSb
• 分子量: 570.118
• InChiKey: YKZPEWDMPOKGQX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2-呋喃甲胺 、 rac-diphenyl[(N,N,N-trimethylaminomethylferrocenyl)iodide]stibine 在 K₂CO₃ 作用下， 以 乙腈 为溶剂， 生成 diphenyl[2-(furan-2-ylmethylamino)methylferrocen-1-yl]stibine
  参考文献：
  名称：

  New 1,2-disubstituted ferrocenyl stibines containing N-heterocyclic pendant arm: Sb–N hypervalent compounds

  摘要：

  New 1,2-disubstituted ferrocenyl stibines viz. containing -CH2NR or -CH2NHR pendant arm at the ortho-position have been synthesized and characterized by various physicochemical methods. These new ferrocenylstibines were prepared by the nucleophilic substitution reaction of diphenyl[(N,N,N-trimethylaminomethylferrocenyl)iodide]stibine by different primary amines and secondary heterocyclic amines viz. furan-2-ylmethylamine, p-aminoacetophenone, 3-(1-hydroxyethyl)-aniline, 4-hydroxypiperidine, 1-ethylpiperazine and 4-(4-bromophenyl)-4-hydroxypiperidine. Molecular structure of stibine (2), (3), (5) and (7) have been determined by X-ray crystallography. Stibine (2), (5) and (7) show a weak hypervalent Sb-N interaction while stibine (3) does not show this interaction in solid state. (c) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2009.01.051