[Mo(HN=CPh2)(η3-C3H5)(CO)2(phen)]B(3,5-bis(trifluoromethyl)phenyl)4 | 423170-57-4

• 英文名称: [Mo(HN=CPh2)(η3-C3H5)(CO)2(phen)]B(3,5-bis(trifluoromethyl)phenyl)4
• CAS: 423170-57-4
• 化学式: C₃₀H₂₄MoN₃O₂*C₃₂H₁₂BF₂₄
• 分子量: 1417.7
• InChiKey: LWNGKWCOZVQYFP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  二苯甲酮亚胺 、 [Mo(CF₃SO₃)(η³-C₃H₅)(CO)₂(1,10-phenanthroline)] 、 四(3,5-二(三氟甲基)苯基)硼酸钠 以 二氯甲烷 为溶剂， 以78%的产率得到[Mo(HN=CPh2)(η3-C3H5)(CO)2(phen)]B(3,5-bis(trifluoromethyl)phenyl)4
  参考文献：
  名称：

  An Easily Accessed Molybdenum Lewis Acid as a Catalyst for Imine Aziridination

  摘要：

  The complex [MoCl(eta(3)-C3H5)(CO)(2)(phen)] was prepared in a one-pot manner from Mo(CO)(6), allyl chloride, and 1,10-phenanthroline (phen). This complex reacted with AgOTf to afford [Mo(OTf)(eta(3)-C3H5)(CO)(2)(phen)] (1). The reaction of 1 with NaBAr'(4) (Ar' = 3,5-bis(trifluoromethyl)phenyl) in CH2Cl2 yielded a solution that catalyzed (1% load of the catalyst) the reaction of ethyl diazoacetate with N-benzylideneaniline to give a mixture of cis(carboxyethyl)-1,3-diphenylaziridine and two enamines. Replacement of phen by chiral ligands based on trans-1,2-diaminocyclohexane failed to induce asymmetry on the obtained aziridine.

  DOI：

  10.1021/om010958i