dimethyl[4-tert-butyl-2,6-bis-(phenyliminomethylene)-phenolato] gallium | 885329-26-0

• 英文名称: dimethyl[4-tert-butyl-2,6-bis-(phenyliminomethylene)-phenolato] gallium
• CAS: 885329-26-0
• 化学式: C₂₆H₂₉GaN₂O
• 分子量: 455.252
• InChiKey: HZDHMHBZOGBOQZ-DCVPUTJBSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  4-tert-butyl-2,6-bis(phenyliminomethylene)-phenol 、 三甲基镓 以 苯 为溶剂， 以76%的产率得到dimethyl[4-tert-butyl-2,6-bis-(phenyliminomethylene)-phenolato] gallium
  参考文献：
  名称：

  Synthesis and characterization of gallium complexes bearing 4-alkyl-2,6-bis(aryliminomethylene)-phenol ligands; crystal structure of dimethyl[4-methyl-2,6-bis-(p-methylphenyliminomethylene)-phenolato]gallium

  摘要：

  Eight new dimethylgallium complexes bearing 4-alkyl-2.6-bis(aryliminomethlene))-phenol ligands of type Me2GaL (L = 4-methyl-2, 6-bis-(phenyliminomethylene)-phenolato (3); L = 4-methyl-2,6-bis-(p-methylphenyliminomethylene)-phejiolato (4); L = 4-methyl-2,6-bis-(1-naphthyliminomethylene)- phenolato (5); L = 4-methyl-2,6-bis-(2-chlorophenyliminomethylene)-phenolato (6); 4-tert-butyl-2,6-bis(phenyliminomethylene)-phenolato (7); L = 4-tert-butyl-2.6-bis-)-methylphenyliminomethylene)-phenolato (8); L = 4-tert-butyl-2,6bis-(1-naphthyliminomethylene)-phenolato (9); and L = 4-tert-butyl-2,6-bis-(2-chlorophenyliminomethylene)-phenolato](3) have been synthesized by the reaction of trimethylgallium with appropriate phenol. The complexes obtained have been characterized by elemental analysis, 'H NMR, IR and mass spectroscopy, respectively. The solid-state structures of dimethyl[4-methyl-2,6-bis-(p-methylphenyliminomethylene)-phenolato]gallium (4) have been determined by X-ray single crystal analysis. In the structure, Ga atom is coordinated by one nitrogen atom and the other nitrogen atom remains constant. The distorted tetrahedron geometry around gallium is presented. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2005.11.048