bis((isopropyldimethylsilyl)tetramethylcyclopentadienyl)titanium(II) | 879549-45-8

• 英文名称: bis((isopropyldimethylsilyl)tetramethylcyclopentadienyl)titanium(II)
• 英文别名: bis(η5-tetramethyl(isopropyldimethylsilyl)cyclopentadienyl)titanium(II)；[Ti(η5-C5Me4(SiMe2(Pr(i)))2]
• CAS: 879549-45-8
• 化学式: C₂₈H₅₀Si₂Ti
• 分子量: 490.756
• InChiKey: LZYJGXJJLJGWCD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  bis((isopropyldimethylsilyl)tetramethylcyclopentadienyl)titanium(II) 以 甲苯 为溶剂， 以84%的产率得到[Ti(η5-tetramethyl(isopropyldimethylsilyl)cyclopentadienyl)(η3:η4-C5Me2(SiMe2(i-Pr))(CH2)2)]
  参考文献：
  名称：

  Effect of the Trimethylsilyl Substituent on the Reactivity of Permethyltitanocene

  摘要：

  The presence of a trimethylsilyl substituent in place of one of the methyl groups of each of the cyclopentadienyl ligands of decamethyltitanocene enhances the thermal stability of the resulting complex, [Ti-II{eta(5)-C5Me4(SiMe3)}(2)] (1), and controls the products formed in thermolysis of its methyl derivatives. Titanocene 1 was found to be stable in toluene solution up to 90 degrees C, while under vacuum at 140 degrees C it liberated hydrogen to give the asymmetrical doubly tucked-in titanocene [Ti-II{eta(3):eta(4)-C5Me2(SiMe3)(CH2)(2)}{eta(5)-C5Me4(SiMe3)}] (3). The mono- and dimethyl derivatives of 1, the complexes [(TiMe)-Me-III{eta(5)-C5Me4(SiMe3)}(2)] (5) and [(TiMe2)-Me-IV{eta(5)-C5Me4(SiMe3)}(2)] (6), undergo thermolysis at lower temperature than do the corresponding permethyltitanocene derivatives and eliminate hydrogen from their trimethylsilyl group. Thus, the known [Ti-III{eta(5):eta(1)-C5Me4(SiMe2CH2)}{eta(5)-C5Me4(SiMe3)}] (4) was obtained from 5, and compound 6 afforded [Ti-II{eta(6):eta(1)-C5Me3(CH2)(SiMe2CH2)}{eta(5)-C5Me4(SiMe3)}] (7) at only 90 degrees C, both with liberation of methane. Crystal structures of 3, 5, and 7 were determined. DFT calculations for titanocene 1 revealed that the metal-cyclopentadienyl bonding is accomplished via a three-center-four-electron orbital interaction. An auxiliary long-range Si-C bond interaction with the Ti center was also established, providing a reason for the enhanced thermal stability of 1. The molecular orbitals participating in the exo methylene-titanium bonds for 3 and 7 are also three-centered and are compatible with the assignment of their activated ligands to eta(3):eta(4)-allyldiene and eta(6)-fulvene structures, respectively. Qualitatively, the much higher thermal stability of 3 and 7 compared to that of 1 is due to the exploitation of four d orbitals in the bonding molecular orbitals for 3 and 7 versus only two d orbitals for 1.

  DOI：

  10.1021/om070159l
• 作为产物：
  描述：

  [Ti(η5-C6Me4(SiMe2(Pr(i))2(η2-btmse)] 以 neat (no solvent, solid phase) 为溶剂， 以67%的产率得到bis((isopropyldimethylsilyl)tetramethylcyclopentadienyl)titanium(II)
  参考文献：
  名称：

  异丙基二甲基甲硅烷基取代的八甲基噻吩并茂的合成与结构

  摘要：

  isopropyldimethylsilyl取代的二氯二茂钛的还原[的TiCl 2（η 5 -C 5我4森达2镨我）2 ]（1）通过在过量之二的存在过量的镁（三甲基硅烷基）乙炔（btmse）的四氢呋喃在60℃下得到的产物的混合物在他们之中只有三核的Ti -镁-钛氢化-桥连的络合物镁钛[Ti（μ-H）2（η 5 -C 5我4森达2镨我）] 2（3）中的分离和表征。二茂钛的前体，钛[Ti（η 5-C 5我4森达2镨我）2（η 2 -btmse）]（6），由同一个系统中获得的，其初始形成的[后的TiCl（η 5 -C 5我4森达2镨我）2 ]（2），在-18℃下反应过夜，然后将溶液与剩余的镁快速分离。二茂钛钛[Ti（η 5 -C 5我4森达2镨我）2 ]（7通过在真空中在75°C下6的热解获得）。的晶体结构1，2，3，6，和7进行了测定。

  DOI：

  10.1016/j.jorganchem.2005.10.018