(phenethyl 8-quinolyl sulfide)dichloropalladium(II) | 444673-50-1

• 英文名称: (phenethyl 8-quinolyl sulfide)dichloropalladium(II)
• CAS: 444673-50-1
• 化学式: C₁₇H₁₅Cl₂NPdS
• 分子量: 442.705
• InChiKey: KDHFHTREIGEYNY-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  sodium tetrachloropalladate(II) trihydrate 、 8-(phenethylthio)quinoline 以 乙醇 为溶剂， 以85%的产率得到(phenethyl 8-quinolyl sulfide)dichloropalladium(II)
  参考文献：
  名称：

  Synthesis and crystal structures of palladium(II) complexes containing benzyl 8-quinolyl sulfide and phenethyl 8-quinolyl sulfide

  摘要：

  Four palladium(II) complexes [PdX2(L-N,S)] (X = Cl, Br; L: BzSq = benzyl 8-quinolyl sulfide, PheneSq = phenethyl 8-quinolyl sulfide) were prepared. The crystal structure of [PdCl2(BzSq-N,S)] revealed the presence of an intraligand stacking between the phenyl and quinolyl groups of BzSq. This stacking interaction was confirmed even in Me2SO, MeCN and MeNO2. On the other hand, [PdCl2(PheneSq-N,S)] did not show such an intraligand stacking both in the solid and in solutions. (C) 2002 Published by Elsevier Science Ltd.

  DOI：

  10.1016/s0277-5387(02)00864-1