trimethyl(5,6-benzoquinoline) gallium(III) | 169897-51-2

• 英文名称: trimethyl(5,6-benzoquinoline) gallium(III)
• CAS: 169897-51-2
• 化学式: C₁₆H₁₈GaN
• 分子量: 294.049
• InChiKey: YSZJSVWNUCJJSN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  5.6-苯并喹啉 、 三甲基镓 以 乙醚 为溶剂， 以78%的产率得到trimethyl(5,6-benzoquinoline) gallium(III)
  参考文献：
  名称：

  Synthesis and characterization of adducts of R3M (R  Me, M  Al, Ga In) with 5,6-benzoquinoline: X-ray crystal structures of Me3GaBQ and ClMe2AlBQ (BQ = 5,6-benzoquinoline)

  摘要：

  The reaction of R(3)M and AlMe(2)Cl with 5,6-benzoquinoline (BQ) gave the Lewis acid-base adducts R(3)M-BQ [R = Me, M = Al (1), Ga (2), In (3)] and ClMe(2)Al-BQ (4). These adducts are much less air- and water-sensitive than the metal trialkyls and AlMe(2)Cl. All the compounds were characterized by elemental analyses, IR, NMR and mass spectroscopy. The X-ray crystal structures of 2 and 4 showed that gallium and aluminium atoms in the molecule were tetrahedrally coordinated.

  DOI：

  10.1016/0277-5387(95)00007-f