1-(9-trimethylsilyl-9-fluorenyl)-3,7,10-trimethylgermatrane | 226903-36-2

• 英文名称: 1-(9-trimethylsilyl-9-fluorenyl)-3,7,10-trimethylgermatrane
• CAS: 226903-36-2
• 化学式: C₂₅H₃₅GeNO₃Si
• 分子量: 498.233
• InChiKey: WVNQJQHUZXMHCR-AQNXPRMDSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  9-tribromogermyl-9-trimethylsilylfluorene 、 tris(2-tributylstannoxypropyl)amine 以 氯仿 为溶剂， 以95%的产率得到1-(9-trimethylsilyl-9-fluorenyl)-3,7,10-trimethylgermatrane
  参考文献：
  名称：

  Synthesis and Characterisation of 1-[9-(H, Me3Si, Me3Ge, Me3Sn)9-Fluorenyl]-3,7,10-trimethylgermatranes. The Crystal Structure Analysis of 1-(9-Fluorenyl)-3,7,10-trimethylgermatrane

  摘要：

  The title compounds, viz. C13H8(R)Ge . (OCHMeCH2)(3)N (1: R = H, 2: R = Me3Si; 3: R = Me3Ge) were prepared as mixtures of diastereomers by the reaction of N(CH(2)CHMeOSnAlk(3))(3) (7: Alk = Et; 8: Alk = Bu) with C13H8(R)GeBr3 (4: R=H, 5: R=Me3Si; 6: R=Me3Ge), respectively. The synthesis of C13H8(Me3Sn)Ge (OCHMeCH2)(3)N (13) by the reaction of germatrane (1) with Me3SnNMe2 is reported. Identity and structures were established by elemental analyses,H-1 and C-13 NMR spectroscopy and mass spectrometry. The crystal structure of 1 was determined by X-ray diffraction methods.

  DOI：

  10.1002/(sici)1521-3749(199904)625:4<655::aid-zaac655>3.0.co;2-n