| 184916-76-5

• CAS: 184916-76-5
• 化学式: C₃₀H₃₂Ga₂N₂
• 分子量: 560.043
• InChiKey: IVDCOXVRJCMPPE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  二苄胺 、 三甲基镓 以 甲苯 为溶剂， 以65%的产率得到
  参考文献：
  名称：

  Synthesis and Molecular Structure of an Orthometalated Aminogallane, [MeGaN(CH₂C₆H₄)(CH₂Ph)]₂

  摘要：

  Monitoring the thermolysis reaction of Me(3)Ga with HN(CH(2)Ph)(2) in toluene with multinuclear NMR spectroscopy indicates the initial formation of [Me(2)GaN(CH(2)Ph)(2)](2) via 1,2elimination of CH4 followed by additional 1,2-elimination steps that give the orthometalated gallium dimer [MeGaN(CH2C6H4)(CH(2)Ph)](2) in 65% yield. This is the first reported example of orthometalation of an aromatic ring carbon by gallium. Because [MeGaN(CH2C6H4)(CH(2)Ph)](2) forms prior to the complete conversion of (PhCH(2))(2)NH . GaMe(3) to [Me(2)GaN(CH(2)Ph)(2)](2), thermolysis of a Me(3)Ga/HN(CH(2)Ph)(2) mixture is not a viable route to [Me(2)GaN(CH(2)Ph)(2)](2). Instead it was prepared by a salt elimination reaction. The single-crystal X-ray diffraction analysis establishes the dimeric nature of the orthometalated compound and indicates a structure that is consistent with the NMR chemical shift assignements obtained using both 1-D and 2-D NMR techniques.

  DOI：

  10.1021/om9604381