[(silver) (Ph2N(i-Pr)Ph(OC6H3Me2-2,6))2] hexafluorophosphate | 917571-80-3

• 英文名称: [(silver) (Ph2N(i-Pr)Ph(OC6H3Me2-2,6))2] hexafluorophosphate
• CAS: 917571-80-3
• 化学式: C₅₈H₆₂AgN₂O₂P₄*F₆P
• 分子量: 1195.87
• InChiKey: MSXVIMXIDCAOMZ-APRURGOBSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  ammonium hexafluorophosphate 、 1-(2,6-dimethylphenoxy)-N-(diphenylphosphino)-N-isopropyl-1-phenylphosphinamine 、 silver nitrate 以 乙腈 为溶剂， 以70%的产率得到[(silver) (Ph2N(i-Pr)Ph(OC6H3Me2-2,6))2] hexafluorophosphate
  参考文献：
  名称：

  An unexpected entry into the silver(I) chemistry of diphosphazane ligands: Crystal and molecular structures of [Ag{Ph2PN(Pri)PPh2}(CF3SO3)]2, [Ag{Ph2PN(Pri)PPh(OC6H3Me2-2,6)}2]PF6, and [Ag3(μ-Cl)2{Ph2PN(R)PPh2}3]PF6 (R=H, Pri)

  摘要：

  Mononuclear, binuclear and trinuclear silver(l) complexes were obtained unexpectedly while probing the reactivity of diphosphazane ligands of the type X2PN(Pr-i)PXY towards the ruthenium-based precursor Ru(bipy)(2)Cl-2 center dot 2H(2)O, in the presence of a silver salt as a chloride scavenger. Subsequently, the reactions of AgX [X = Cl, NO3 or CF3SO3] with Ph2PN(R)PPh(Y) [R = H, Y = Ph; R = Pr-i, Y = Ph or OC6H3Me2-2,6] in a 1: 1 or 1:2 molar ratio have been investigated. Mononuclear or binuclear Ag(I) complexes containing either chelating or bridging diphosphazane ligands are obtained. Trinuclear silver(l) complexes are accessible by the treatment of diphosphazane ligands, Ph2PN(R)PPh2 [R = H, Pr-i] with AgCl using piperidine as the solvent. In the presence of a suitable chloride donor species, the mononuclear and binuclear complexes of Ph2PN(Pr-i)PPh2 are transformed slowly to the trinuclear complex [Ag-3(mu-Cl)(2){Ph2PN(Pr-i)PPh2}(3)]X, over a period 20 h. The structures of representative complexes have been confirmed by X-ray crystallography and the salient structural features are discussed. (C) 2006 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2006.05.017