[ZnBr(4-chloro-2-[(3-(morpholin-4-yl)propylimino)methyl]phenolate)] | 1603047-92-2

• 英文名称: [ZnBr(4-chloro-2-[(3-(morpholin-4-yl)propylimino)methyl]phenolate)]
• CAS: 1603047-92-2
• 化学式: C₁₄H₁₈BrClN₂O₂Zn
• 分子量: 427.056
• InChiKey: WRWIZGWRKUNLAA-RPVSWQTKSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  4-chloro-2-[(3-morpholin-4-yl-propylimino)-methyl]-phenol 、 zinc dibromide 以 甲醇 为溶剂， 反应 0.5h， 以36%的产率得到[ZnBr(4-chloro-2-[(3-(morpholin-4-yl)propylimino)methyl]phenolate)]
  参考文献：
  名称：

  Syntheses, crystal structures, and fluorescence properties of Zinc(II) complexes with multi-dentate Schiff bases

  摘要：

  Two new structurally similar mononuclear Schiff base zinc(II) complexes, [ZnBr(ClMP)] (I) and [ZnCl(NMP)] (II) (ClMP = 4-chloro-2-[(3-morpholin-4-ylpropylimino)methyl]phenolate; NMP = 4-nitro-2-[(3-morpholin-4-ylpropylimino)methyl]phenolate), and two new dinuclear Schiff base zinc(II) complexes, [Zn-2(EMP)(2)I-2] (III), and [Zn-2(MPA)(CH3OH)(2)(N-3)(2)] (IV) (EMP = 5-diethylamino-2-[(2-dimethylaminoethylimino)methyl]phenolate; MPA = N,N'-bis(3-methoxysalicylidene)propane-1,3-diamine), have been prepared and characterized mainly by single-cyrstal X-ray diffraction. Complex I crystallizes in the monoclinic space group P2(1)/n with unit cell dimensions: a = 15.116(3), b = 9.465(1), c = 23.714(4) , beta = 104.358(2)A degrees, V = 3286.9(8) (3), Z = 8, R (1) = 0.0439, and wR (2) = 0.0736. Complex II crystallizes in the monoclinic space group P2(1)/c with unit cell dimensions: a = 7.253(2), b = 16.652(4), c = 13.568(3) , beta = 96.600(2)A degrees, V = 1627.8(6) (3), Z = 4, R (1) = 0.0417, and wR (2) = 0.0809. Complex III crystallizes in the monoclinic space group C2/c with unit cell dimensions: a = 27.962(2), b = 8.246(2), c = 31.605(3) , beta = 90.343(2)A degrees, V = 7287.4(15) (3), Z = 8, R (1) = 0.0721, and wR (2) = 0.1709. Complex IV crystallizes in the monoclinic space group C2/c with unit cell dimensions: a = 20.483(3), b = 11.344(2), c = 14.909(3) , beta = 131.650(1)A degrees, V = 2588.6(7) (3), Z = 4, R (1) = 0.0343, and wR (2) = 0.0792. Each Zn atom in I and II are four-coordinated in a tetrahedral geometry by the NNO donor set of the Schiff base ligand and one halide atom. The Zn atoms in III are in square pyramidal coordination, and those in IV are in octahedral and tetrahedral coordination. Thermal stability and fluorescence properties of the complexes I and II have also been determined.

  DOI：

  10.1134/s1070328413110080