([(SiMe3)2NC(NCHMe2)2]2Nd(μ-Cl))2 | 611183-57-4

• 英文名称: ([(SiMe3)2NC(NCHMe2)2]2Nd(μ-Cl))2
• CAS: 611183-57-4
• 化学式: C₅₂H₁₂₈Cl₂N₁₂Nd₂Si₈
• 分子量: 1505.74
• InChiKey: IVWLGZJYOGDNKU-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  ([(SiMe3)2NC(NCHMe2)2]2Nd(μ-Cl))2 、 lithium diisopropyl amide 以 正己烷 为溶剂， 以78%的产率得到[(SiMe3)2NC(NCHMe2)2]2NdN(CHMe2)2
  参考文献：
  名称：

  Synthesis and characterization of bis(guanidinate)lanthanide diisopropylamido complexes

  摘要：

  Treatment of LnCl(3) with [(SiMe3)(2)NC(NiPr)(2)]Li in 1:2 molar ratio afforded the soluble bis(guanidinate)lanthanide chlorides {[(SiMe3)(2)NC(NiPr)(2)](2)Ln(mu-Cl)}(2) (Ln=Y (1), Nd (2)). Amination of 1 and 2 with two equivalents of LiN(iPr)(2) in a mixture solution of toluene and hexane gave [(SiMe3)(2)NC(NiPr)(2)](2)LnN(iPr)(2) (Ln -Y (3), Nd (4)) in good isolated yields. The single-crystal structural analyses of 2 and 3 revealed that the coordination geometries of lanthanide metals are best described as a distorted pseudo-octahedron and a pseudo-pyramid, respectively. Complexes 3 and 4 exhibited extremely high activity for the polymerizations of epsilon-caprolactone and methyl methacrylate (MMA). (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(03)00600-4
• 作为产物：
  描述：

  三氯化钕 、 Li[(Me₃Si)₂NC(NⁱPr)₂] 以 甲苯 为溶剂， 以76%的产率得到([(SiMe3)2NC(NCHMe2)2]2Nd(μ-Cl))2
  参考文献：
  名称：

  Synthesis and characterization of bis(guanidinate)lanthanide diisopropylamido complexes

  摘要：

  Treatment of LnCl(3) with [(SiMe3)(2)NC(NiPr)(2)]Li in 1:2 molar ratio afforded the soluble bis(guanidinate)lanthanide chlorides {[(SiMe3)(2)NC(NiPr)(2)](2)Ln(mu-Cl)}(2) (Ln=Y (1), Nd (2)). Amination of 1 and 2 with two equivalents of LiN(iPr)(2) in a mixture solution of toluene and hexane gave [(SiMe3)(2)NC(NiPr)(2)](2)LnN(iPr)(2) (Ln -Y (3), Nd (4)) in good isolated yields. The single-crystal structural analyses of 2 and 3 revealed that the coordination geometries of lanthanide metals are best described as a distorted pseudo-octahedron and a pseudo-pyramid, respectively. Complexes 3 and 4 exhibited extremely high activity for the polymerizations of epsilon-caprolactone and methyl methacrylate (MMA). (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(03)00600-4