| 1356826-18-0

• CAS: 1356826-18-0
• 化学式: C₁₈H₂₃ClN₄Pd
• 分子量: 437.28
• InChiKey: DHEGHUHSXCEDLS-SERMZQFOSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  sodium tetrachloropalladate(II) 、 N',N'-diethyl-N-(2-phenyldiazenylphenyl)ethane-1,2-diamine 以 甲醇 为溶剂， 以60%的产率得到
  参考文献：
  名称：

  Synthesis, characterization and structure of new diazoketiminato chelates of palladium(II): Potential catalyst for C–C coupling reactions

  摘要：

  The 1N-(N,N-diethylaminoethyl)-2-arylazoaniline, HL [where HL = ArN = NC6H4N(H){C2H4N(C2H5)(2)}: Ar = C6H5 (for HL1), p-MeC6H4 (for HL2) or p-ClC6H4 (for HL3)], ligands were prepared by treating the appropriate 2-(arylazo)aniline with 2-bromo-N,N-diethylethanamine. Reactions of Na2PdCl4 with HL afforded the [(L)PdCl] complexes. HL binds palladium(II) in a tridentate fashion (N,N,N), forming a new diazoketiminato chelate. The X-ray structure of [(L-3)PdCl] was determined to confirm the characterization. The newly synthesized complex [(L-1)Pdl] was utilized to carry out Suzuki and Heck reactions for a variety of substrates. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2011.11.026