trans-bis(η2-ethene)tetracarbonyltungsten(I)(1+) | 423769-70-4

• 英文名称: trans-bis(η2-ethene)tetracarbonyltungsten(I)(1+)
• 英文别名: trans-W(CO)4(η(2)-C2H4)2(1+)
• CAS: 423769-70-4；425373-89-3
• 化学式: C₈H₈O₄W
• 分子量: 351.999
• InChiKey: ZBDKKLBSDQGCCL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  trans-bis(η2-ethene)tetracarbonyltungsten(0) 在 tert-butylammonium hexafluorophosphate(V) 作用下， 以 二氯甲烷 为溶剂， 生成 trans-bis(η2-ethene)tetracarbonyltungsten(I)(1+)
  参考文献：
  名称：

  Isomeric Olefin Tetracarbonyl Complexes of Tungsten(I):  An Infrared Spectroelectrochemical Study at Low Temperatures

  摘要：

  In situ electrolysis within an optically transparent thin-layer electrochemical (OTTLE) cell was applied at 293-243 K in combination with FTIR spectroscopy to monitor spectral changes in the carbonyl stretching region accompanying oxidation of four tetracarbonyl olefin complexes of tungsten(0), viz., trans-[W(CO)(4)(eta(2)-ethene)(2)], trans-[W(CO)(4)(eta(2)-norbornene)(2)], [W(CO)(4)(eta(4)-cycloocta-1,5-diene)], and [W(CO)(4)(eta(4)-norbornadiene)]. In all cases, the one-electron-oxidized radical cations (17-electron complexes) have been identified by their characteristic nu(CO) patterns. For the bidentate diene ligands, the cis stereochemistry is essentially fixed in both the 18- and 17-electron complexes. The radical cation of the trans-bis(ethene) complex was observed only at 243 K, while at room temperature it isomerized rapidly to the corresponding cis-isomer. The thermal stability of the three studied radical cations in the cis configuration correlates with the relative strength of the W-CO bonds in the positions trans to the olefin ligand, which are more affected by the oxidation than the axial W-CO bonds. For the bulky norbornene ligands, their trans configuration in the bis(norbornene) complex remains preserved after the oxidation in the whole temperature range studied. The limited thermal stability of the radical cations of the trans-bis(alkene) complexes is ascribed to dissociation of the alkene ligands. The spectroelectrochemical results are in very good agreement with data obtained earlier by DFT (B3LYP) calculations.

  DOI：

  10.1021/om700384g