[MeGa(Cl)OnBu]3 | 1069132-83-7

• 英文名称: [MeGa(Cl)OnBu]3
• CAS: 1069132-83-7
• 化学式: C₁₅H₃₆Cl₃Ga₃O₃
• 分子量: 579.977
• InChiKey: ZEWZMFKBUJMGAP-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  二甲基镓氯化物 、 正丁醇 以 甲苯 为溶剂， 以59%的产率得到[MeGa(Cl)OnBu]3
  参考文献：
  名称：

  Organoalkoxochlorogallane

  摘要：

  AbstractOrganoalkoxochlorogallanesMe2GaCl was treated with nBuOH and iBuOH in a molar ration of 1:2, respectively. However, only one equivalent of the alcohol reacted with MeGaCl2 to give [MeGa(Cl)OnBu]3 (1) or [MeGa(Cl)OiBu]3 (2). 1 and 2 were characterized by NMR and IR techniques as well as by X‐ray structure determinations. According to that 1 and 2 form trimers in solution and the solid state. In solution both isomers Cs and C3v were observed while the trimers exist only as Cs isomers in the solid state which exhibit strongly distorted boat conformations with a disorder of the Cl/Me position at one of the gallium atoms.

  DOI：

  10.1002/zaac.200700124